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Nanofluidic transport inside carbon nanotubes

机译:碳纳米管内部的纳米流体传输

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摘要

Using non-equilibrium molecular dynamics simulations, we investigate the effects of nanotube size, mean flow velocity, ion concentration and temperature of an electrolyte water solution on shearing stress and nominal viscosity. It is shown that the distributed electric field arising from the electrolyte water solution has significant influences on fluid properties. Also, the temperature of the solution, which causes thermal movement, affects nanofluidic transport in nanoenvironments. The nominal viscosity and shearing stress increases as the tube diameter increases. When the temperature of solution increases or ion concentration decreases, the shearing stress and nominal viscosity increase. Simultaneous effects of ion concentration and temperature depict that the temperature effect is more dominant and these two parameters cannot be superposed. The molecular mechanisms that affect such behaviours are considered by studying radial density and radial velocity profiles in different cases.
机译:使用非平衡分子动力学模拟,我们研究了纳米管尺寸,平均流速,离子浓度和电解质水溶液温度对剪切应力和标称粘度的影响。结果表明,由电解质水溶液产生的分布电场对流体性能有很大影响。同样,引起热运动的溶液温度会影响纳米环境中的纳米流体传输。标称粘度和剪切应力随着管直径的增加而增加。当溶液温度升高或离子浓度降低时,剪切应力和标称粘度会增加。离子浓度和温度的同时影响表明温度影响更为明显,并且这两个参数不能叠加。通过研究不同情况下的径向密度和径向速度分布,可以考虑影响此类行为的分子机制。

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