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首页> 外文期刊>Journal of Physics, D. Applied Physics: A Europhysics Journal >Preparation and photoluminescence properties of Sm3+-doped ZrO2 nanotube arrays
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Preparation and photoluminescence properties of Sm3+-doped ZrO2 nanotube arrays

机译:掺Sm3 +的ZrO2纳米管阵列的制备及光致发光性能

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摘要

Zr-Sm (3 at.% Sm) alloy was prepared through a powder metallurgical method. Sm3+-doped ZrO2 nanotube arrays have been achieved directly by anodizing the Zr-Sm alloy. The effects of electrolyte and annealing temperature on the morphologies and structures of the nanotube arrays were studied. The photoluminescence properties of Sm3+-doped ZrO2 nanotube arrays prepared in aqueous solution and formamide + glycerol solution were studied in detail as well. Results show that tetragonal ZrO2 promoted the photoluminescence efficiency of this system. Under excitation at 407 nm, the sample prepared in aqueous solution annealed at 600 degrees C displayed the strongest emission peak at 571 nm, corresponding to the 4G(5/2) -> H-6(5/2) samarium transition.
机译:通过粉末冶金法制备Zr-Sm(3 at。%Sm)合金。掺杂Sm3 +的ZrO2纳米管阵列已通过阳极氧化Zr-Sm合金直接获得。研究了电解质和退火温度对纳米管阵列的形貌和结构的影响。还详细研究了在水溶液和甲酰胺+甘油溶液中制备的掺杂Sm3 +的ZrO2纳米管阵列的光致发光特性。结果表明,四方ZrO2促进了该系统的光致发光效率。在407 nm激发下,在600摄氏度下退火的水溶液中制备的样品在571 nm处显示出最强的发射峰,对应于4G(5/2)-> H-6(5/2)transition跃迁。

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