首页> 外文期刊>International Journal of Biological Macromolecules: Structure, Function and Interactions >Development of new organic-inorganic, hybrid bionanocomposite from cellulose and clay for enhanced removal of Drimarine Yellow HF-3GL dye
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Development of new organic-inorganic, hybrid bionanocomposite from cellulose and clay for enhanced removal of Drimarine Yellow HF-3GL dye

机译:从纤维素和粘土中研制新的有机无机,杂交脱硫二酮复合材料,提高脱摩汀黄色HF-3GL染料去除

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Cellulose/clay composites were prepared and applied for the adsorption of Drimarine Yellow HF-3GL direct dye. The prepared composites were characterized by FTIR, TGA, EDX, SCM and XRD techniques. Bagasse was used as a cellulose source, while clay was obtained from local source, which was modified chemically before composite preparation. Adsorption efficiencies were compared of composite I and II as a function of contact time, temperature, pH, initial dye concentration and composite dose. Non-linear kinetic and equilibrium isotherm employed and dye adsorption data fitted well to pseudo-second order kinetics model. Among isotherms, the Redlich-Peterson isotherm well defined the sorption process of dye on to composites. Thermodynamic factors (Delta S degrees, Delta H degrees and Delta G degrees) revealed that the sorption process was spontaneous, exothermic and feasible. Cellulose/clay composite I and II removed 88.64% and 89.95% dye with 60 min at pH 2 and 30 degrees C, respectively. For reusability, desorption was performed using different eluting agents and NaOH showed higher desorption efficiency. For the treatment of wastewater, the developed composites were applied to textile effluents and color removal of (90-96.07%) and (97-98.23%) was achieved using cellulose/clay composite I and II. respectively. The results showed that cellulose/clay composite are efficient for the removal dyes and could possibly be used for the treatment of textile effluents. (C) 2020 Elsevier B.V. All rights reserved.
机译:制备纤维素/粘土复合材料并施加脱摩尔黄色HF-3GL直接染料的吸附。制备的复合材料的特征在于FTIR,TGA,EDX,SCM和XRD技术。甘蔗渣被用作纤维素源,而粘土从局部源获得,在复合制剂之前经化学改性。将复合I和II的吸附效率与接触时间,温度,pH,初始染料浓度和复合剂剂量的函数进行比较。非线性动力学和平衡等温线采用和染料吸附数据,适用于伪二阶动力学模型。在等温线中,雷尔里希 - 彼得逊等温线很好地定义了染料的复合材料的吸附过程。热力学因素(三角洲,δH度和三角洲G度)揭示了吸附过程是自发的,放热和可行的。纤维素/粘土复合物I和II分别除去88.64%和89.95%染料,分别在pH 2和30℃下以60分钟除去。为了可重复使用,使用不同的洗脱剂和NaOH表现出更高的解吸效率进行解吸。为了处理废水,使用纤维素/粘土复合I和II施加开发的复合材料并施加到纺织品污水和颜色去除(90-96.07%)和(97-98.23%)。分别。结果表明,纤维素/粘土复合材料对于去除染料是有效的,并且可能用于治疗纺织品流出物。 (c)2020 Elsevier B.v.保留所有权利。

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