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首页> 外文期刊>International Journal of Quantum Chemistry >Substituent effects at nitrogen/phosphorus atoms of dialkaline earth metal complexes: Excess electron and large second‐hyperpolarizability
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Substituent effects at nitrogen/phosphorus atoms of dialkaline earth metal complexes: Excess electron and large second‐hyperpolarizability

机译：二烷基地球金属配合物氮/磷原子的取代基效应：过量的电子和大二次超极化性

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Abstract > A number of imido‐, amido‐, and phosphido‐bridged dialkaline earth metal (M?=?Be, Mg, and Ca) complexes and their alkali metal (Li and Na) derivatives have been considered to study the ground state structure and the second‐hyperpolarizability. The calculated ground state geometries contain four‐membered M?N(P)?M?N(P) ring having either planar or butterfly‐like bent structure. The second‐hyperpolarizability has been calculated at the HF and CCSD(T) levels using Sadlej's pol and aug‐pc‐2 basis sets, respectively. The addition of second hydrogen/alkali metal atom on nitrogen/phosphorus (N/P) atom substantially reduces the charge transfer from the alkaline earth metal atoms as the high negative charge on N/P exerts stronger push effect on the outermost electron pair in the “ns” sub‐shell of M. The excess electron density on the alkaline earth metal atoms plays a crucial role in the enhancement of second‐hyperpolarizability. The sum‐over‐state method calculated two‐photon contribution of second‐hyperpolarizability has been found to be significant. The variation of second‐hyperpolarizability has been explained satisfactorily in terms of the TD‐CAMB3LYP calculated spectroscopic properties in the light of two‐state model. The calculated mean second‐hyperpolarizabilities of alkali substituted amido‐ and phosphido‐bridged complexes are in the order of 10 7 au. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”xml：lang =“en”> <title type =“main”>抽象</ title> >许多iniido-，amido-和磷化铜桥偶尔卡莱林土金属（m？ =？是，Mg和Ca）复合物及其碱金属（Li和Na）衍生物已经考虑研究地态结构和第二超极化性。计算出的接地状态几何形状含有四元的M？n（p）αm≤n（p）环，其具有平面或蝴蝶状弯曲结构。使用Sadlej的POL和Aug-PC-2基集在HF和CCSD（T）水平上计算了第二个超极化性。在氮气/磷（N / P）原子上添加第二氢/碱金属原子基本上降低了碱土金属原子的电荷转移，因为N / P对最外电子对的高负电荷施加更强的推动效应“NS”亚壳的M.碱土金属原子上的过量电子密度在增强二倍体的增强中起着至关重要的作用。已经发现总和过态方法计算了二级高分子化的二光子贡献是显着的。在两种状态模型的光线下，在TD-CAMB3LYP计算的光谱性质方面已经令人满意地解释了第二超极化性的变化。计算的碱的碱性二苯基和磷酸酯和磷酸桥络合物的计算的平均二极管均为10 7 </ sup> au。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-21753/'>《International Journal of Quantum Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2019年第15期</span><b style="margin: 0 2px;">|</b><span>共15页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Banerjee Paramita&option=202" target="_blank" rel="nofollow">Banerjee Paramita;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hatua Kaushik&option=202" target="_blank" rel="nofollow">Hatua Kaushik;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mondal Avijit&option=202" target="_blank" rel="nofollow">Mondal Avijit;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nandi Prasanta K.&option=202" target="_blank" rel="nofollow">Nandi Prasanta K.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryIndian Institute of Engineering Science and TechnologyShibpur Howrah India;</p> <p>Department of ChemistryIndian Institute of Engineering Science and TechnologyShibpur Howrah India;</p> <p>Department of ChemistryIndian Institute of Engineering Science and TechnologyShibpur Howrah India;</p> <p>Department of ChemistryIndian Institute of Engineering Science and TechnologyShibpur Howrah India;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=dialkaline earth metal bridged complexes&option=203" rel="nofollow">dialkaline earth metal bridged complexes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=excess electron&option=203" rel="nofollow">excess electron;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=second‐hyperpolarizability&option=203" rel="nofollow">second‐hyperpolarizability;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=TD‐CAMB3LYP&option=203" rel="nofollow">TD‐CAMB3LYP;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=two‐photon contribution&option=203" rel="nofollow">two‐photon contribution;</a> </p> <div class="translation"> 机译：二烷基地球金属桥接复合物;过量电子;二次超极化;TD-CAMB3LYP;双光子贡献; 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href="/academic-journal-cn_chinese-journal-applied-chemistry_thesis/0201298369102.html">有机磷化合物的质谱研究 Ⅹ.1,2-二苯基-3,3-二烷基-2,5-二氧-1,4,2-二氮磷杂环戊烷的EI质谱研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邱丰和&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 邱丰和</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宋凤瑞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,宋凤瑞</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘淑莹&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘淑莹</a> <span> <a href="/journal-cn-54377/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 应用化学 </a> </span> <span> . 1993</span><span>,第1期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-central-china-normal-university-natural-science-edition_thesis/0201293050422.html">具有生物活性的有机磷化合物研究——I.O,O-二烷基-N-烷基-N-(二烷胺基羰基)甲基硫代磷酰胺酯的合成、性质和杀螨活性</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李志荣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李志荣</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘钊杰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘钊杰</a> <span> <a href="/journal-cn-50188/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 华中师范大学学报：自然科学版 </a> </span> <span> . 1991</span><span>,第3期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chemical-journal-chinese-universities_thesis/0201231661180.html">O-乙基-O-(取代γ-丁内酯基-α-次甲基N-烷基(或N，N-二烷基)硫代磷酰胺酯类化合物的合成</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈茹玉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈茹玉</a> <span> <a href="/journal-cn-10958/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高等学校化学学报 </a> </span> <span> . 1990</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-jianghan-university-natural-science-edition_thesis/0201249880619.html">磷-氮协效型烷基次膦酸盐阻燃剂的合成及其在PBT中的应用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杜大江&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 杜大江</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=曹芳利&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,曹芳利</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈佳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈佳</a> <span> <a href="/journal-cn-4648/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 江汉大学学报（自然科学版） </a> </span> <span> . 2015</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-29995_thesis/020222300724.html">新型杂原子配位促进的稀土金属-氮键均裂单电子还原反应研究:含N,N-二甲基胺基丙基取代茚基二价镱(铕)络合物的合成及催化活性研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周双六&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 周双六</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=金属有机化学国家重点实验室&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,金属有机化学国家重点实验室</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王绍武&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王绍武</a> <span> <a href="/conference-cn-29995/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十二届全国金属有机化学会议 </a> <span> <span> . 2002</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315979633.html">双磷杂环戊二烯及双对磷杂对甲基环丁二烯双铬羰基配合物中磷原子孤电子对对结构的影响研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=万鑫&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 万鑫</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201704379.html">包含卡宾-过渡金属配合物发射体和至少一种选自二甲硅烷基咔唑、二甲硅烷基二苯并呋喃、二甲硅烷基二苯并噻吩、二甲硅烷基二苯并磷杂环戊二烯、二甲硅烷基二苯并噻吩S-氧化物和二甲硅烷基二苯并噻吩S,S-二氧化物的化合物的有机发光二极管</a> <b>[P]</b> . <span> 中国专利： CN101878552B </span> <span> . 2015.07.15</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120106093958.html">包含卡宾-过渡金属配合物发射体和至少一种选自二甲硅烷基咔唑、二甲硅烷基二苯并呋喃、二甲硅烷基二苯并噻吩、二甲硅烷基二苯并磷杂环戊二烯、二甲硅烷基二苯并噻吩S-氧化物和二甲硅烷基二苯并噻吩S,S-二氧化物的化合物的有机发光二极管</a> <b>[P]</b> . <span> 中国专利： CN101878552A </span> <span> . 2010-11-03</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130429235503.html">New polymer, containing heteroaromatic units respectively with at least two nitrogen- or phosphorus atoms or at least one nitrogen- and at least one phosphorus atoms, useful e.g. in fuel cells, batteries, capacitors, and solar cells</a> <b>[P]</b> . <span> 外国专利： <!-- 德国专利： --> DE102009014906A1 </span> <span> . 2009-10-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：含有例如分别具有至少两个氮或磷原子或至少一个氮和至少一个磷原子的杂芳族单元的新聚合物。在燃料电池，电池，电容器和太阳能电池中 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130475457096.html">PROCESS FOR MANUFACTURING HERBICIDAL PHOSPHORUS COMPOUNDS,IN WHICH PHOSPHORUS ATOM IS LINKED WITH NITROGEN ATOM VIA CARBON ATOM</a> <b>[P]</b> . <span> 外国专利： <!-- --> PL123998B1 </span> <span> . 1982-12-31</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在磷原子与氮原子通过碳原子连接的除草剂磷化合物的制备方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130478859349.html">PROCESS FOR MANUFACTURING HERBICIDAL PHOSPHORUS COMPOUNDS,IN WHICH PHOSPHORUS ATOM IS LINKED WITH NITROGEN ATOM VIA CARBON ATOM</a> <b>[P]</b> . <span> 外国专利： <!-- --> PL214793A1 </span> <span> . 1980-01-02</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在磷原子与氮原子通过碳原子连接的除草剂磷化合物的制备方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon 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