Heterobimetallic Sodium Rare-Earth Complexes: 'Third-Generation' MOCVD Precursors for the Deposition of NaREF4 (RE = Y, Gd) Films

Battiato Sergio; Rossi Patrizia; Paoli Paola; Malandrino Graziella

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Heterobimetallic Sodium Rare-Earth Complexes: 'Third-Generation' MOCVD Precursors for the Deposition of NaREF4 (RE = Y, Gd) Films

机译：异质酸钠稀土配合物：“第三代”MOCVD前体，用于沉积NareF4（RE = Y，GD）薄膜

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We report the synthesis of novel hetero-bimetallic precursors of the formula [RE(hfa)(4)](-)[Na center dot tetraglyme](+) [RE = Y, Gd; Hhfa = 1,1,1,5,5,5-hexafluoro-2,4-pentanedione; tetraglyme = 2,5,8,11,14-pentaoxapentadecane], which can be efficiently used as a single source for the metal-organic chemical vapor deposition of NaREF4 films.

机译：我们报道了式的新型杂生双金属前体的合成[Re（HFA）（4）]（ - ）[Na中心点Tetraglyme]（+）[Re = Y，Gd; HHFA = 1,1,1,5,5,5-六氟氟-2,4-戊尼基奥; Tetraglyme = 2,5,8,11,14-五苯己烷基烷]，可有效地用作NareF4薄膜金属 - 有机化学气相沉积的单一来源。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2018年第24期|共5页
作者
Battiato Sergio; Rossi Patrizia; Paoli Paola; Malandrino Graziella;
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Univ Catania Dipartimento Sci Chim Viale A Doria 6 I-95125 Catania Italy;

Univ Firenze Dipartimento Ingn Ind Via Santa Marta 3 I-50136 Florence Italy;

Univ Firenze Dipartimento Ingn Ind Via Santa Marta 3 I-50136 Florence Italy;

Univ Catania Dipartimento Sci Chim Viale A Doria 6 I-95125 Catania Italy;

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中图分类化学;
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1. Heterobimetallic Sodium Rare-Earth Complexes: "Third-Generation" MOCVD Precursors for the Deposition of NaREF4 (RE = Y, Gd) Films [J] . Battiato Sergio, Rossi Patrizia, Paoli Paola, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2018,第24期

机译：异质酸钠稀土配合物：“第三代”MOCVD前体，用于沉积NareF4（RE = Y，GD）薄膜
2. Heterobimetallic d-f Metal Complexes as Potential Single-Source Precursors for MOCVD: Structure and Thermodynamic Study of the Sublimation of [Ni(salen)Ln(hfa)_3], Ln = Y, Gd [J] . Alain Gleizes, Miguel Julve, Natalia Kuzmina, European journal of inorganic chemistry . 1998,第8期

机译：异双金属d-f金属配合物作为MOCVD的潜在单源前体：[Ni（salen）Ln（hfa）_3]升华的结构和热力学研究，Ln = Y，Gd
3. Heterobimetallic Ba-Co aminopolycarboxylate complexes as precursors for BaCoO_(3-δ) oxides; towards a one-stage-deposition of cobaltite films [J] . Ion Bulimestru, Olivier Mentre, Nathalie Tancret Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology . 2010,第47期

机译：异双金属Ba-Co氨基聚羧酸盐配合物作为BaCoO_（3-δ）氧化物的前体;一步沉积钴膜
4. MOCVD of gallium oxide thin films using homoleptic gallium complexes:precursor evaluation and thin film characterisation [C] . M. Hellwig, K. Xu, D. Barreca, EuroCVD 17/CVD 17 . 2009

机译：使用均相镓配合物的氧化镓薄膜的MOCVD：前体评估和薄膜表征
5. The Development of Novel-Single Source Precursors for the Growth of Zinc Oxide Thin Films via Atmospheric Pressure Metal Organic Chemical Vapor Deposition (AP-MOCVD) For Applications in Microelectronic Devices. [D] . Johnson, Keneshia Onekia. 2013

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6. Synthesis and Characterization of Tungsten Nitrido Amido Guanidinato Complexes as Precursors for Chemical Vapor Deposition of WNxCy Thin Films [O] . Michelle M. Nolan, Alexander J. Touchton, Nathaniel E. Richey, -1

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7. Deposition and Characterisation of Nitrogen-Doped Zinc Oxide Thin Films by MOCVD Using Zinc Acetate—Ammonium Acetate Precursor [O] . U. S. Mbamara, O.O. Akinwumi, E.I. Obiajunwa, 2012

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Heterobimetallic Sodium Rare-Earth Complexes: 'Third-Generation' MOCVD Precursors for the Deposition of NaREF4 (RE = Y, Gd) Films

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