Lanthanide complexes of a cross-bridged cyclam ligand: Isolation and structural characterization of unusual trinuclear mu(3)-imido Yb(III) cluster cations and a mixed valence Yb(II/III) salt containing an Yb(II) anion

OConnor PE; Twamley B; Berg DJ

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Lanthanide complexes of a cross-bridged cyclam ligand: Isolation and structural characterization of unusual trinuclear mu(3)-imido Yb(III) cluster cations and a mixed valence Yb(II/III) salt containing an Yb(II) anion

机译：交叉桥接旋风环的镧系元素：异常三核μ（3）-imido Yb（III）簇的分离和结构表征，含有Yb（II）阴离子的混合价Yb（II / III）盐

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The reaction of the cross-bridged cyclam ligand H2CBC with divalent ytterbium precursors, Yb[N(SiMe3)(2)](2)[L](2) (L = THF or Et2O) or Yb(C5Me5)(2)(OEt2) afforded polymeric [Yb(CBC)](n) (1), as the primary product. In addition, the Yb[N(SiMe3)(2)](2)[L](2) reactions also afforded a small amount of an unusual mixed valence salt containing a trinuclear Yb(III) cluster cation featuring a triply bridging NH group and a mononuclear Yb(II) anion, {[Yb(CBC)](3) [mu(3)-NH]}(+) {Yb[N(SiMe3)(2)](3)}(-) (2). A related cluster containing an iodide counterion, {[Yb(CBC)](3)[mu(3)-NH]}(+) I- (3), was also isolated in one case. The structures of salts 2 and 3 were determined by X-ray crystallography. Reaction of [Yb(CBC)](n) with p-tolyldisulfide, (C6H4MeS)(2), produced burgundy crystals of [Yb(CBC)S-p-C6H4Me)](n) (4). The H-1 NMR spectra of 2 suggests that the trinuclear cation remains intact in THF-d(8) solution. (c) 2005 Elsevier B.V. All rights reserved.

机译：交叉桥循环配体H2CBC与二价镱前体的反应，Yb [n（SIME3）（2）]（2）[L]（2）（L = THF或ET 2 O）或Yb（C5ME5）（2）（ OET2）提供聚合物[Yb（CBC）]（N）（N）（1），作为初级产物。另外，Yb [n（SIME3）（2）]（2）[L]（2）反应还得到少量含有三核YB（III）簇的异常混合价盐，其具有三级桥接NH组和单核Yb（II）阴离子，{[Yb（CBC）]（3）[亩（3）-NH]}（+）{YB [n（SIME3）（2）]（3）}（ - ）（ 2）。含有碘化物抗衡离子的相关簇，{[Yb（CBC）]（3）[亩（3）-NH]}（+）I-（3），在一种情况下也被隔离。通过X射线晶体学确定盐2和3的结构。 [Yb（CBC）]（N）与对甲苯二甲酸二硫化物（C6H4ME）（2）的反应，产生的[Yb（CBC）S-P-C6H4ME）（N）（4）产生的勃艮第晶体]（4）。 H-1 NMR光谱的表明，ThF-D（8）溶液中的三核阳离子保持完整。（c）2005年Elsevier B.v.保留所有权利。

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《Inorganica Chimica Acta》 |2006年第9期|共9页
作者
OConnor PE; Twamley B; Berg DJ;
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Univ Victoria Dept Chem Victoria BC V8W 3V6 Canada;

Univ Idaho Univ Res Off Single Crystal Xray Diffract Lab Moscow ID 83844 USA;

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正文语种 eng
中图分类生物体其他化学成分;
关键词
x-ray crystal structures; ytterbium complexes; imide; mixed valence; macrocyclic ligands; cyclam; amide; trinuclear cluster; EARTH-METAL COMPLEXES; RAY CRYSTAL-STRUCTURE; ORGANOMETALLIC COMPOUNDS; TETRAAMINE LIGANDS; ORGANOLANTHANIDE CHEMISTRY; COPPER(II) COMPLEXES; ZINC(II) COMPLEXES; YTTERBIUM; REACTIVITY; AMIDO;

机译：X射线晶体结构;ytterbium络合物;酰亚胺;混合效果;醋酸醋栗;酰胺;酰胺;临核簇;射线晶体络合物;射线晶体结构;有机金属化合物;四胺配体;铜（II）复合物;铜（II）配合物;锌（ii）复合物;镱;反应性;amido;

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1. Lanthanide complexes of a cross-bridged cyclam ligand: Isolation and structural characterization of unusual trinuclear mu(3)-imido Yb(III) cluster cations and a mixed valence Yb(II/III) salt containing an Yb(II) anion [J] . OConnor PE, Twamley B, Berg DJ Inorganica Chimica Acta . 2006,第9期

机译：交叉桥接旋风环的镧系元素：异常三核μ（3）-imido Yb（III）簇的分离和结构表征，含有Yb（II）阴离子的混合价Yb（II / III）盐
2. Structural and Photophysical Properties of Coordination Networks Combining [Ru(Bpym)(CN)_4]~(2-) or [{Ru(CN)_4}_2(mu-bpym)]~(4-) Anions (bpym = 2,2'-Bipyrimidine) with Lanthanide(III) Cations: Sensitized Near-Infrared Luminescence from Yb(III),Nd(III [J] . Juan-Manuel Herrera, Simon J.A.Pope, Harry Adams, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2006,第10期

机译：结合[Ru（Bpym）（CN）_4]〜（2-）或[{Ru（CN）_4} _2（mu-bpym）]〜（4-）阴离子的配位网络的结构和光物理性质（bpym = 2， 2'-联嘧啶）与镧系元素（III）阳离子：Yb（III），Nd（III）的敏化近红外发光
3. A new heteroatom coordination promoted homolysis of the Yb-N bond. Synthesis and structural characterization of a new class of ytterbium(II) and ytterbium(III) complexes with amido and indenyl ligands and catalytic activities of ytterbium(II) complex [J] . Sheng EH., Wang SW., Yang GS., Organometallics . 2003,第4期

机译：一种新的杂原子配位促进了Yb-N键的均质化。新型am基和茚基配体的（（II）和（III）配合物的合成，结构表征及catalytic（II）配合物的催化活性
4. Highly Enantioselective Diels-Alder Reactions of Danishefsky's-type Dienes with Electron-Deficient Alkenes Catalyzed by Yb(III)-BINAMIDE Complexes [C] . Daisuke Shirasaki, Yukinori Sudo, Shinji Harada Symposium on Organometallic Chemistry . 2007

机译：Danishefsky的二烯酰胺酰胺反应达到易用的Yb（III） - 苯胺配合物催化的电子缺乏烯烃
5. Part I. Syntheses and characterization of hydrogen-bridged lanthanide(II)-boron complexes. Part II. Syntheses and characterization of cyanide-bridged lanthanide(III)-palladium complexes. [D] . Lim, Soyoung. 2001

机译：第一部分：氢桥联镧系元素（II）-硼配合物的合成与表征。第二部分氰化物桥联的镧系元素（III）-钯配合物的合成与表征。
6. Structural and photophysical studies on ternary Sm(III) Nd(III) Yb(III) Er(III) complexes containing pyridyltriazole ligands [O] . Alexey N. Gusev, Victor F. Shul’gin, Svetlana B. Meshkova, -1

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7. Structural and photophysical studies on ternary Sm(III), Nd(III), Yb(III), Er(III) complexes containing pyridyltriazole ligands [O] . Gusev Alexey N., Shul’gin Victor F., Meshkova Svetlana B., 2012

机译：含吡啶基三唑配体的三元Sm（III），Nd（III），Yb（III），Er（III）配合物的结构和光物理研究

Lanthanide complexes of a cross-bridged cyclam ligand: Isolation and structural characterization of unusual trinuclear mu(3)-imido Yb(III) cluster cations and a mixed valence Yb(II/III) salt containing an Yb(II) anion

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