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首页> 外文期刊>Inorganica Chimica Acta >Synthesis, characterization, coordination chemistry, and luminescence studies of copper, silver, palladium, and platinum complexes with a phosphorus/nitrogen/phosphorus ligand
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Synthesis, characterization, coordination chemistry, and luminescence studies of copper, silver, palladium, and platinum complexes with a phosphorus/nitrogen/phosphorus ligand

机译：用磷/氮/磷配体的铜，银，钯和铂复合物的合成，表征，配位化学和发光研究

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摘要

Complexes of copper, silver, platinum, and palladium with N,N-bis[2-(diphenylphosphino)ethyl]-phenylamine (a PNP ligand) have been synthesized and characterized by H-1 NMR, P-31{H-1} NMR, HRMS, Elemental Analysis, and X-ray Crystallography. NMR data that were obtained at various temperatures resulted in different patterns in terms of peak multiplicity and coupling constants. Absorption and luminescence behaviors were reported, NMR and MS data were discussed and the coordination modes were investigated. The platinum complex that was synthesized in the present study was found to be a trans complex (by X-ray diffraction and P-31{H-1} NMR data) contrary to the P-31{H-1} NMR data for the cis isomer published last year in the literature by Kostas I. D. et al.
机译：用N，N-BIS [2-（二苯基膦基）乙基] - 苯胺（PNP配体）的铜，银，铂和钯和钯的复合物已被合成，并以H-1 NMR，P-31 {H-1}特征在一起。 NMR，HRMS，元素分析和X射线晶体学。 在各种温度下获得的NMR数据导致峰值多重和耦合常数方面的不同模式。 报告了吸收和发光行为，讨论了NMR和MS数据，并研究了协调模式。 发现在本研究中合成的铂络合物是反式复合物（通过X射线衍射和P-31 {H-1} NMR数据）与P-31 {H-1} NMR数据相反 CIS ISOMER去年在KOSTAS ID等人的文献中发表。

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