> Aminotroponiminates (ATIs) are monoanionic ligands with an N , N ‐binding pocket and a rigid, planar, unsaturated, C '/> New Perspectives for Aminotroponiminates: Coordination Chemistry, Redox Behavior, Cooperativity, and Catalysis
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首页> 外文期刊>European journal of inorganic chemistry >New Perspectives for Aminotroponiminates: Coordination Chemistry, Redox Behavior, Cooperativity, and Catalysis
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New Perspectives for Aminotroponiminates: Coordination Chemistry, Redox Behavior, Cooperativity, and Catalysis

机译：氨基杀氧质杀药物的新视角：协调化学，氧化还原行为，合作和催化

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> Aminotroponiminates (ATIs) are monoanionic ligands with an N , N ‐binding pocket and a rigid, planar, unsaturated, C 7 ‐ring as a ligand backbone. Recent findings show that this ligand backbone can play an active role in coordination chemistry, redox reactions, and ligand‐centered reactivity of ATI complexes. Based on these results, ATIs have been recognized as redox‐active and cooperative ligands, which has implications for existing and potential future applications of ATI compounds in synthesis, catalysis, and materials science. The catalytic applications of ATI complexes are summarized in this Microreview, including results from the fields of hydroamination, epoxidation, cyanosilylation, ε‐caprolactone‐, olefin‐, epoxide‐, and epoxide/CO 2 (co‐)polymerization as well as electron transfer catalysis. Furthermore, recent advances in the use of ATI ligands for stabilizing heavy analogs of carbon oxo compounds are showcased.
机译： >氨管酰胺（ATIS）是单一的配体，其具有 n ， n - 粘合口袋和刚性，平面，不饱和，c <子> 7 -ring作为配体骨干网。最近的发现表明，这种配体骨架可以在协调化学，氧化还原反应和亚麻配合物的配体中心反应性中发挥积极作用。基于这些结果，ATIS已被认为是氧化还原活性和合作配体，这对ATI化合物在合成，催化和材料科学中的存在和潜在的未来应用具有影响。 ATI复合物的催化应用总结在该微腔中，包括水焦，环氧化，氰化物，ε-己内酯，烯烃，环氧化物，环氧化物和环氧化物/ CO 2 （共同）聚合以及电子转移催化。此外，揭示了用于稳定用于稳定碳氧化合物的重物的ATI配体的最新进展。

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