Reactivity of a (Benzene)Ruthenium(II) Cation on a Di‐lacunary γ‐Keggin‐Type Silicotungstate and Synthesis of a Mono‐(Benzene)Ruthenium(II)‐Attached γ‐Keggin‐Type Silicotungstate

Kikuchi Masaya; Ota Hiromi; López Xavier; Nakaya Toshimi; Tsunoji Nao; Sano Tsuneji; Sadakane Masahiro

首页> 外文期刊>European journal of inorganic chemistry >Reactivity of a (Benzene)Ruthenium(II) Cation on a Di‐lacunary γ‐Keggin‐Type Silicotungstate and Synthesis of a Mono‐(Benzene)Ruthenium(II)‐Attached γ‐Keggin‐Type Silicotungstate

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Reactivity of a (Benzene)Ruthenium(II) Cation on a Di‐lacunary γ‐Keggin‐Type Silicotungstate and Synthesis of a Mono‐(Benzene)Ruthenium(II)‐Attached γ‐Keggin‐Type Silicotungstate

机译：（苯）钌（II）阳离子对Di-Livunaryγ-Keggin型硅钨酸盐的反应性和单 - （苯）钌（II）的合成 - Attachedγ-Keggin型硅钨酸盐

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> Reaction of a (benzene)Ru 2+ complex, [Ru(C ₆ H ₆ )Cl ₂ ] ₂ , with a di‐lacunary γ‐Keggin‐type silicodecatungstate, K ₈ [γ‐SiW ₁₀ O ₃₆ ], at a (C ₆ H ₆ )Ru 2+ /[γ‐SiW ₁₀ O ₃₆ ] 8– ratio of 1 produces [γ‐SiW ₁₀ O ₃₆ Ru(C ₆ H ₆ )] 6– . The cesium salt was characterized using experimental and theoretical methods; one (C ₆ H ₆ )Ru 2+ moiety is attached through three bridging oxygen atoms of the non‐lacunary site, and the anion is stable in aqueous solution. 1 H NMR spectroscopy and high‐resolution electrospray ionization mass spectrometry measurements of the reaction mixture with different (C ₆ H ₆ )Ru 2+ /[γ‐SiW ₁₀ O ₃₆ ] 8– ratios indicate that the (C ₆ H ₆ )Ru 2+ complex first reacts with the three bridging oxygen atoms to form [γ‐SiW ₁₀ O ₃₆ Ru(C ₆ H ₆ )] 6– , and then react on the terminal oxygen atoms of the lacunary site to form a [γ‐SiW

机译：<抽象类型= “主”> >一个（苯）的反应的Ru ^{2 + 复合物，的[Ru（C <子> 6 ħ<子> 6 ）氯<子> 2 ] <子> 2 ，与二缺位γ-Keggin型silicodecatungstate，K <子> 8 [γ-硅钨酸<子> 10 < /子> 0 <子> 36 ]，在（C <子> 6 ħ<子> 6 ）的Ru ^{2 + / [γ-硅钨酸<子> 10 0 <子> 36 ] ^{8 - 的1比产生[γ-硅钨酸<子> 10 0 <子> 36 < /子>茹（C <子> 6 ħ<子> 6 ）] ^{6 - 。使用实验和理论方法的铯盐进行表征;一个（C <子> 6 ħ<子> 6 ）的Ru ^{2 + 部分是通过三个桥接非缺位站点的氧原子连接，并且所述阴离子为稳定在水溶液中。将反应混合物的^{1 H NMR光谱和高分辨率电喷雾电离质谱测量结果与不同（C <子> 6 ħ<子> 6 ）的Ru ^{2 + / [γ-硅钨酸<子> 10 0 <子> 36 ] ^{8 - 比值表明（C <子> 6 ħ<子> 6 ）的Ru ^{2 + 复杂第一发生反应的三个桥接氧原子形成[γ-硅钨酸<子> 10 0 <子> 36 茹（C <子> 6 ħ<子> 6 ）] ^{6 - ，然后在缺位网站的终端氧原子形成的反应一个[γ-硅钨酸}}}}}}}}}}

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来源
《European journal of inorganic chemistry》 |2018年第17期|共9页
作者
Kikuchi Masaya; Ota Hiromi; López Xavier; Nakaya Toshimi; Tsunoji Nao; Sano Tsuneji; Sadakane Masahiro;
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作者单位

Department of Applied ChemistryHiroshima University1‐4‐1 Kagamiyama 739‐8527 Higashi‐Hiroshima Japan;

Division of Instrumental AnalysisOkayama University700‐8530 Okayama Japan;

Departament de Química Física i InorgànicaUniversitat Rovira i VirgiliMarcel·lí Domingo 1 43007 Tarragona Spain;

Department of Applied ChemistryHiroshima University1‐4‐1 Kagamiyama 739‐8527 Higashi‐Hiroshima Japan;

Department of Applied ChemistryHiroshima University1‐4‐1 Kagamiyama 739‐8527 Higashi‐Hiroshima Japan;

Department of Applied ChemistryHiroshima University1‐4‐1 Kagamiyama 739‐8527 Higashi‐Hiroshima Japan;

Department of Applied ChemistryHiroshima University1‐4‐1 Kagamiyama 739‐8527 Higashi‐Hiroshima Japan;

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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Polyoxometalates; γ‐Keggin silicotungstates; Ruthenium; Isomers;

机译：多氧化素;γ-Keggin硅钨酸盐;钌;异构体;

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1. Reactivity of a (Benzene)Ruthenium(II) Cation on a Di‐lacunary γ‐Keggin‐Type Silicotungstate and Synthesis of a Mono‐(Benzene)Ruthenium(II)‐Attached γ‐Keggin‐Type Silicotungstate [J] . Kikuchi Masaya, Ota Hiromi, López Xavier, European journal of inorganic chemistry . 2018,第17期

机译：（苯）钌（II）阳离子对Di-Livunaryγ-Keggin型硅钨酸盐的反应性和单 - （苯）钌（II）的合成 - Attachedγ-Keggin型硅钨酸盐
2. Reactivity of a (Benzene)Ruthenium(II) Cation on a Di‐lacunary γ‐Keggin‐Type Silicotungstate and Synthesis of a Mono‐(Benzene)Ruthenium(II)‐Attached γ‐Keggin‐Type Silicotungstate [J] . Kikuchi Masaya, Ota Hiromi, López Xavier, European journal of inorganic chemistry . 2018,第17期

机译：（苯）钌（II）阳离子对Di-Livunaryγ-Keggin型硅钨酸盐的反应性和单 - （苯）钌（II）的合成 - Attachedγ-Keggin型硅钨酸盐
3. Front Cover: Reactivity of a (Benzene)Ruthenium(II) Cation on a Di‐lacunary γ‐Keggin‐Type Silicotungstate and Synthesis of a Mono‐(Benzene)Ruthenium(II)‐Attached γ‐Keggin‐Type Silicotungstate (Eur. J. Inorg. Chem. 17/2018) [J] . Kikuchi Masaya, Ota Hiromi, López Xavier, European journal of inorganic chemistry . 2018,第17期

机译：前盖：（苯）钌（II）溶液对二层γ-Keggin型硅钨酸盐的反应性和单（苯）钌（II）的合成 - Attachedγ-Keggin型硅钨酸盐（EUR。J. 。inorg。化学。17/2018）
4. Keggin-type mono-lacunary polyoxotungstate catalyst PW11 for the oxidation of benzothiophene in emulsion [C] . Yongna Zhang, Zongxuan Jiang, Hongying Lü, ICEC 2010;International conference on environmental catalysis . 2010

机译：用于乳化液中苯并噻吩氧化的Keggin型单腔聚氧钨酸盐催化剂PW11
5. Photochemistry of group 8 metal complexes of type [M(bpy)2 cyanogen] (M = iron, ruthenium). Photosynthesis of heteroleptic iron(II) compounds and photoionization of ruthenium(II) compounds, or, Photoassisted synthesis of heteroleptic iron(II) compounds and photoionization of ruthenium(II) complexes. [D] . Turner, David Benjamin. 2009

机译：[M（bpy）2氰基]类型的第8组金属配合物的光化学（M =铁，钌）。杂合铁（II）化合物的光合作用和钌（II）化合物的光电离，或者杂合铁（II）化合物的光辅助合成和钌（II）配合物的光电离。
6. Synthesis and Reactivity of Cyclopentadienyl Ruthenium(II)Complexes with Tris(alkylthio)benzenes: Transformation between Dinuclearand Sandwich-Type Complexes [O] . Rong Fan, Ryo Sumitani, Tomoyuki Mochida 2020

机译：环戊二烯基钌（II）的合成与反应活性与三（烷硫基）苯的配合物：双核之间的转化和三明治型复合物
7. Reactivity of a (Benzene)Ruthenium(II) Cation on a Di-lacunary γ-Keggin-Type Silicotungstate and Synthesis of a Mono-(Benzene)Ruthenium(II)-Attached γ-Keggin-Type Silicotungstate [O] . Masaya Kikuchi, Hiromi Ota, Xavier López, 2018

机译：（苯）钌（II）阳离子对Di-Livunaryγ-Keggin型硅钨酸盐的反应性和单 - （苯）钌（II）的合成 - Attachedγ-Keggin型硅钨酸盐

Reactivity of a (Benzene)Ruthenium(II) Cation on a Di‐lacunary γ‐Keggin‐Type Silicotungstate and Synthesis of a Mono‐(Benzene)Ruthenium(II)‐Attached γ‐Keggin‐Type Silicotungstate

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