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首页> 外文期刊>European journal of organic chemistry >Construction of Di(hetero)arylmethanes Through Pd-Catalyzed Direct Dehydroxylative Cross-Coupling of Benzylic Alcohols and Aryl Boronic Acids Mediated by Sulfuryl Fluoride (SO_2F_2)
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Construction of Di(hetero)arylmethanes Through Pd-Catalyzed Direct Dehydroxylative Cross-Coupling of Benzylic Alcohols and Aryl Boronic Acids Mediated by Sulfuryl Fluoride (SO_2F_2)

机译:通过PD催化的直接脱羟基甲烷的苄醇和硫磺氟化芳烃(SO_2F_2)介导的芳族醇和芳族硼酸的直接脱羟基乙烷基甲烷的构建(SO_2F_2)

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摘要

A practical Pd-catalyzed direct dehydroxylative coupling of (hetero)benzylic alcohols with (hetero)arylboronic acids for the constructions of di(hetero)arylmethane derivatives under SO_2F_2 was described. This new method provided a strategically distinct approach to di(hetero)arylmethane derivatives from readily available and abundant benzylic alcohols under mild condition.
机译:描述了在SO_2F_2下的DI(杂)芳基甲烷衍生物的(杂)芳基硼酸的(杂)苄醇的直接脱羟基乙烯酸(杂)苄醇的直接脱羟基偶联偶联偶联偶氮酸的直接脱羟基酸偶联。 这种新方法提供了在轻度条件下从容易获得的和丰富的苄基醇的DI(杂)芳基甲烷衍生物的策略性不同的方法。

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  • 作者单位

    State Key Laboratory of Silicate Materials for Architectures;

    and School of Chemistry Chemical Engineering and Life Science Wuhan University of Technology Wuhan Hubei Province 430070 People's Republic of China;

    State Key Laboratory of Silicate Materials for Architectures;

    and School of Chemistry Chemical Engineering and Life Science Wuhan University of Technology Wuhan Hubei Province 430070 People's Republic of China;

    State Key Laboratory of Silicate Materials for Architectures;

    and School of Chemistry Chemical Engineering and Life Science Wuhan University of Technology Wuhan Hubei Province 430070 People's Republic of China;

    State Key Laboratory of Silicate Materials for Architectures;

    and School of Chemistry Chemical Engineering and Life Science Wuhan University of Technology Wuhan Hubei Province 430070 People's Republic of China;

    State Key Laboratory of Silicate Materials for Architectures;

    and School of Chemistry Chemical Engineering and Life Science Wuhan University of Technology Wuhan Hubei Province 430070 People's Republic of China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 有机化学;
  • 关键词

    Alcohols; Boronic acids; Cross-coupling; Palladium;

    机译:醇类;硼酸;交叉耦合;钯;

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