A Hierarchical Phosphorus Nanobarbed Nanowire Hybrid: Its Structure and Electrochemical Properties

Zhao Dan; Li Beibei; Zhang Jinying; Li Xin; Xiao Dingbin; Fu Chengcheng; Zhang Lihui; Li Zhihui; Li Jun; Cao Daxian; Niu Chunming

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A Hierarchical Phosphorus Nanobarbed Nanowire Hybrid: Its Structure and Electrochemical Properties

机译：分层磷纳米铝瘤纳米线杂种：其结构与电化学性能

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Nanostructured phosphoruscarbon composites are promising materials for Li-ion and Na-ion battery anodes. A hierarchical phosphorus hybrid, SiC@graphene@P, has been synthesized by the chemical vapor deposition of phosphorus on the surfaces of barbed nanowires, where the barbs are vertically grown graphene nanosheets and the cores are SiC nanowires. A temperature-gradient vaporizationcondensation method has been used to remove the unhybridized phosphorus particles formed by homogeneous nucleation. The vertically grown barb shaped graphene nanosheets and a high concentration of edge carbon atoms induced a fibrous red phosphorus (f-RP) growth with its {001} planes in parallel to {002} planes of nanographene sheets and led to a strong interpenetrated interface interaction between phosphorus and the surfaces of graphene nanosheets. This hybridization has been demonstrated to significantly enhance the electrochemical performances of phosphorus.

机译：纳米结构磷碳基复合材料是锂离子和Na离子电池阳极的有希望的材料。通过磷的表面上的化学气相沉积，在倒钩纳米线的表面上的化学气相沉积，倒钩是垂直生长的石墨烯纳米片，并且芯是SiC纳米线的化学气相沉积已经合成了分层磷杂交体。用于去除通过均匀成核形成的未杂交磷颗粒的温度梯度蒸发方法。垂直生长的倒钩形状的石墨烯纳米片和高浓度的边缘碳原子与纳米蛋白板的{001}平面诱导纤维红磷（F-RP）生长，并导致强烈的互通界面相互作用磷和石墨烯纳米片的表面之间。已经证明了这种杂交以显着增强磷的电化学性能。

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来源
《Nano letters》 |2017年第6期|共7页
作者
Zhao Dan; Li Beibei; Zhang Jinying; Li Xin; Xiao Dingbin; Fu Chengcheng; Zhang Lihui; Li Zhihui; Li Jun; Cao Daxian; Niu Chunming;
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作者单位

Xi An Jiao Tong Univ Ctr Nanomat Renewable Energy State Key Lab Elect Insulat &

Power Equipment Sch Elect Engn Xian 710054 Shaanxi Peoples R China;

Xi An Jiao Tong Univ Ctr Nanomat Renewable Energy State Key Lab Elect Insulat &

Power Equipment Sch Elect Engn Xian 710054 Shaanxi Peoples R China;

Xi An Jiao Tong Univ Ctr Nanomat Renewable Energy State Key Lab Elect Insulat &

Power Equipment Sch Elect Engn Xian 710054 Shaanxi Peoples R China;

Xi An Jiao Tong Univ Ctr Nanomat Renewable Energy State Key Lab Elect Insulat &

Power Equipment Sch Elect Engn Xian 710054 Shaanxi Peoples R China;

Xi An Jiao Tong Univ Ctr Nanomat Renewable Energy State Key Lab Elect Insulat &

Power Equipment Sch Elect Engn Xian 710054 Shaanxi Peoples R China;

Xi An Jiao Tong Univ Ctr Nanomat Renewable Energy State Key Lab Elect Insulat &

Power Equipment Sch Elect Engn Xian 710054 Shaanxi Peoples R China;

Xi An Jiao Tong Univ Ctr Nanomat Renewable Energy State Key Lab Elect Insulat &

Power Equipment Sch Elect Engn Xian 710054 Shaanxi Peoples R China;

Xi An Jiao Tong Univ Ctr Nanomat Renewable Energy State Key Lab Elect Insulat &

Power Equipment Sch Elect Engn Xian 710054 Shaanxi Peoples R China;

Xi An Jiao Tong Univ Ctr Nanomat Renewable Energy State Key Lab Elect Insulat &

Power Equipment Sch Elect Engn Xian 710054 Shaanxi Peoples R China;

Xi An Jiao Tong Univ Ctr Nanomat Renewable Energy State Key Lab Elect Insulat &

Power Equipment Sch Elect Engn Xian 710054 Shaanxi Peoples R China;

Xi An Jiao Tong Univ Ctr Nanomat Renewable Energy State Key Lab Elect Insulat &

Power Equipment Sch Elect Engn Xian 710054 Shaanxi Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类特种结构材料;物理化学（理论化学）、化学物理学;
关键词
Hierarchical phosphorus hybrid; red phosphorus; barb-shaped graphene nanosheets; in situ; Li-ion battery;

机译：等级磷杂交;红磷;倒钩形石墨烯纳米片;原位;锂离子电池;

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专利

1. A Hierarchical Phosphorus Nanobarbed Nanowire Hybrid: Its Structure and Electrochemical Properties [J] . Zhao Dan, Li Beibei, Zhang Jinying, Nano letters . 2017,第6期

机译：分层磷纳米铝瘤纳米线杂种：其结构与电化学性能
2. Hierarchical phosphorus hybrids with carbon nanotube veins and black phosphorus skins: Structure and lithium storage properties [J] . Zhao Dan, Zhang Lihui, Fu Chengcheng, Carbon: An International Journal Sponsored by the American Carbon Society . 2018,第期

机译：具有碳纳米管静脉和黑色磷皮肤的等级磷杂交种：结构和锂储存性能
3. Hierarchical Structuring: Phases Hybriding and Hierarchical Structuring of Mesoporous TiO2 Nanowire Bundles for High‐Rate and High‐Capacity Lithium Batteries (Adv. Sci. 7/2015) [J] . Clare P. Grey, Hong-En Wang, Jing Liu, Advanced Science . 2015,第7期

机译：分层结构：用于高速率和大容量锂电池的中孔TiO2纳米线束的相混合和分层结构（Adv。Sci。7/2015）
4. Electrochemical synthesis of CdSe/CdTe nanowires for hybrid photovoltaic structures [C] . Jelena Gurevits, Sergei Bereznev, Valdek Mikli, Materials Research Society Meeting . 2014

机译：混合光伏结构CDSE / CDTE纳米线的电化学合成
5. Synthesis of multisegment nanowire/nanoparticle hybrid biosensors for simultaneous electrochemical detection [D] . Li, Zhiyang. 2018

机译：用于同时电化学检测的多段纳米线/纳米颗粒混合生物传感器的合成
6. Hierarchical Structuring: Phases Hybriding and Hierarchical Structuring of Mesoporous TiO2 Nanowire Bundles for High‐Rate and High‐Capacity Lithium Batteries (Adv. Sci. 7/2015) [O] . Jun Jin, Shao‐Zhuan Huang, Jing Liu, 2015

机译：分层结构：用于高速率和大容量锂电池的中孔TiO2纳米线束的相混合和分层结构（Adv。Sci。7/2015）
7. ZnO Nanowires, Nanotubes, and Complex Hierarchical Structures Obtained by Electrochemical Deposition [O] . Jamil Elias, Johann Michler, Laetitia Philippe, 2011

机译：通过电化学沉积获得的ZnO纳米线，纳米管和复数结构

A Hierarchical Phosphorus Nanobarbed Nanowire Hybrid: Its Structure and Electrochemical Properties

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