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Halbach array assisted assembly of orderly aligned nickel nanowire networks as transparent conductive films

机译:Halbach阵列辅助组装有序对准的镍纳米线网络作为透明导电膜

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摘要

The aspect ratio and arrangement of nanowires play an important role in achieving excellent optoelectronic performance for metal nanowire-based transparent conductive films (TCFs). However, limited to the technology and material properties, studies are always focused on only one of the issues. Here, a novel strategy for manipulating the relative aspect ratio and arrangement of nickel nanowires (NiNWs) at nanoscale by Halbach array assisted assembly technology is introduced. Head-to-tail nickel nanowire chains as large as hundreds of micrometers are formed as a result of the dipole-dipole interactions of wire-wire. The arrangement of nickel nanowires can be preciously controlled by layer-by-layer deposition. Notably, the alignment create a significant improvement on the optoelectronic performance of nickel nanowire TCFs. The optimized orderly aligned NiNWs TCFs demonstrate super optoelectronic performance (90 Omega sq(-1), 86%) than disordered NiNW TCFs (200 Omega sq(-1), 80%). Moreover, NiNW-based TCFs exhibit outstanding long-term oxidation stability at 80 degrees C over 30 d as well as high-temperature oxidization stability even up to 300 degrees C, that is the most stable metal nanowire-based TCFs in air as far as we know. The low-cost, good optoelectronic performance and excellent oxidation resistance of aligned NiNWs will make them as attractive alternatives to silver nanowires for TCFs application.
机译:纳米线的纵横比和布置在实现基于金属纳米线的透明导电膜(TCFS)的优异光电性能方面发挥着重要作用。然而,仅限于技术和材料特性,研究总是专注于其中一个问题。这里,引入了通过Halbach阵列辅助组装技术在纳米级上操纵用于操纵纳米线(ninWs)的相对纵横比和布置的新策略。由于偶极线的偶极偶极相互作用,形成大于数百微米的头部到尾镍纳米线链。镍纳米线的布置可以通过层逐层沉积地精确地控制。值得注意的是,对准为镍纳米线TCFS的光电性能产生显着改善。优化的有序对齐的尼诺TCFS表明超级光电性能(90个Omega Sq(-1),86%)而不是混乱的NinW TCF(200 omega Sq(-1),80%)。此外,基于NINW的TCF在80℃下具有出色的长期氧化稳定性,并且高温氧化稳定性,即使高达300摄氏度,那么最稳定的金属纳米线基TCF在空气中,而且我们知道。低成本,良好的光电性能和对齐的宁珠的优异抗氧化性将使它们作为用于TCFS应用的银纳米线的有吸引力的替代品。

著录项

  • 来源
    《Nanotechnology》 |2019年第35期|共10页
  • 作者单位

    Liaocheng Univ Coll Mat Sci &

    Engn Liaocheng 252059 Shandong Peoples R China;

    Liaocheng Univ Coll Mat Sci &

    Engn Liaocheng 252059 Shandong Peoples R China;

    Liaocheng Univ Coll Mat Sci &

    Engn Liaocheng 252059 Shandong Peoples R China;

    Liaocheng Univ Coll Mat Sci &

    Engn Liaocheng 252059 Shandong Peoples R China;

    Liaocheng Univ Coll Mat Sci &

    Engn Liaocheng 252059 Shandong Peoples R China;

    Liaocheng Univ Coll Mat Sci &

    Engn Liaocheng 252059 Shandong Peoples R China;

    Liaocheng Univ Coll Mat Sci &

    Engn Liaocheng 252059 Shandong Peoples R China;

    Liaocheng Univ Coll Mat Sci &

    Engn Liaocheng 252059 Shandong Peoples R China;

    Natl Ctr Nanosci &

    Technol Key Lab Nanosyst &

    Hierarch Fabricat CAS Ctr Excellence Nanosci Beijing 100190 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 特种结构材料;
  • 关键词

    transparent conductive films; nickel nanowires; orderly aligned; halbach arrays;

    机译:透明导电薄膜;镍纳米线;有序对齐;Halbach阵列;

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