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Rational phase transformation and morphology design to optimize oxygen evolution property of cobalt tungstate

机译:优化钴钨酸盐的氧气演化特性的理性相变性与形态设计

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In this work, a facile and feasible soft template method with the aid of buffer solution is successfully applied to synthesize high-order mesoporous cobalt tungstate for the first time. Attributing to the regulation of reaction solution's pH value and the existence of template, the phenomenon of phase transformation occurs, and high-order mesoporous structure is formed. Because of the variation of phase and morphology, only 448 mV can deliver a current density of 10 mA cm(-2) with a small Tafel slope (61 mV dec(-1)) for mesoporous cobalt tungsten oxide hydroxide, while the cobalt tungstate nanoparticles cannot satisfy the basic demand of electrocatalysts. Herein, rational phase transformation and morphology design can significantly affect the property of oxygen evolution, which can provide vast opportunities to turn into candidates for the novel oxygen evolution catalyst.
机译:在这项工作中,成功地应用了借助缓冲溶液的容易和可行的软模板方法,首次施加了合成高阶中孔钴钨酸酯。 归因于反应溶液的pH值和模板存在的调节,发生相变的现象,形成高阶介孔结构。 由于相和形态的变化,只有448mV可以用小Tafel斜率(61mV Dec(-1))为中孔钴氧化氢氧化物,而钴钨酸酯的小Tafel斜坡(61mV Dec(-1))可以提供10 mA cm(-2)的电流密度。 纳米粒子不能满足电催化剂的基本需求。 在此,合理相变和形态设计可以显着影响氧气进化的性质,这可以提供巨大的机会转变为新型氧气进化催化剂的候选物。

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