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Light scattering and random lasing in aqueous suspensions of hexagonal boron nitride nanoflakes

机译:六边形氮化硼氮化物水悬浮液中的光散射和随机激光

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摘要

Liquid phase exfoliation allows large scale production of 2D materials in solution. The particles are highly anisotropic and strongly scatter light. While spherical particles can be accurately and precisely described by a single parameter-the radius, 2D nanoflakes, however, cannot be so easily described. We investigate light scattering in aqueous solutions of 2D hexagonal boron nitride nanoflakes in the single and multiple scattering regimes. In the single scattering regime, the anisotropic 2D materials show a much stronger depolarization of light when compared to spherical particles of similar size. In the multiple scattering regime, the scattering as a function of optical path for hexagonal boron nitride nanoflakes of a given lateral length was found to be qualitatively equivalent to scattering from spheres with the same diameter. We also report the presence of random lasing in high concentration suspensions of aqueous h-BN mixed with Rhodamine B dye. The h-BN works as a scattering agent and Rhodamine B as a gain medium for the process. We observed random lasing at 587 nm with a threshold energy of 0.8 mJ.
机译:液相剥离允许在溶液中大规模生产2D材料。颗粒是高度各向异性的强烈的散射光。虽然通过单个参数可以精确且精确地描述球形颗粒 - 但是,半径,2D纳米薄饼不能简单地描述。我们在单一和多个散射方案中研究了2D六边形氮化硼纳米薄膜水溶液中的光散射。在单个散射方案中,与类似尺寸的球形颗粒相比,各向异性2D材料显示出更强烈的光偏振。在多个散射方案中,发现作为给定横向长度的六边形氮化硼氮化物纳米薄片的光路的函数的散射质量等同于从具有相同直径的球体散射。我们还报告了与罗丹明B染料混合的高浓度悬浮液中随机激光的存在。 H-BN用作散射剂和罗丹明B作为该方法的增益介质。我们观察到587nm的随机激光,阈值能量为0.8 mj。

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