Substituent-dependent reactivity of triarylantimony(iii) toward I-2: isolation of [Ar3SbI](+)salt

Sharutin Vladimir V.; Sharutina Olga K.; Novikov Alexander S.; Adonin Sergey A.

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Substituent-dependent reactivity of triarylantimony(iii) toward I-2: isolation of [Ar3SbI](+)salt

机译：三芳antimony（III）朝向I-2的取代基 - 2：分离[Ar3Sbi]（+）盐

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The outcome of reactions of triarylantimony (Ar3Sb) with diiodine in benzene is strongly affected by the identity of the substituents. For R = 4-MePh, 3-MePh and 4-FPh, they form Sb(V)derivatives Ar3SbI2, while for (2-MeO-5-BrC6H4)(3)Sb the reaction results in [(2-MeO-5-BrC6H4)(3)SbI](I-3) where I is bound to the Sb center. The features of noncovalent interactions in the structure of the latter compound, as well as the electronic structure of the [(2-MeO-5-BrPh)(3)SbI](+)cation, were studied by theoretical methods.

机译：三芳基锑（Ar3Sb）与二碘在苯中的反应结果受到取代基的特性的强烈影响。对于r = 4-meph，3-meph和4-fph，它们形成Sb（v）衍生物Ar3sbi2，而对于（2-meo-5-brc6h4）（3）Sb，反应结果[（2-meo-5 -BRC6H4）（3）SBI]（I-3）我与SB中心结合的地方。通过理论方法研究了后一种化合物结构的非共价相互作用的特征，以及[（2-MeO-5-BPH）（3）SBI]（+）阳离子的电子结构。

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《New Journal of Chemistry》 |2020年第34期|共4页
作者
Sharutin Vladimir V.; Sharutina Olga K.; Novikov Alexander S.; Adonin Sergey A.;
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South Ural State Univ Lenina St 76 Chelyabinsk 454080 Russia;

South Ural State Univ Lenina St 76 Chelyabinsk 454080 Russia;

St Petersburg State Univ Inst Chem Univ Skaya Nab 7-9 St Petersburg 199034 Russia;

South Ural State Univ Lenina St 76 Chelyabinsk 454080 Russia;

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Substituent-dependent reactivity of triarylantimony(iii) toward I-2: isolation of [Ar3SbI](+)salt

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