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The effect of co-sensitization methods between N719 and boron dipyrromethene triads on dye-sensitized solar cell performance

机译:N719与硼双甲烯三合会在染料敏化太阳能电池性能之间的致敏方法的影响

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摘要

A boron dipyrromethene (BODIPY) featuring triphenylamine triad, BD, has been synthesized as a co-sensitizer in dye-sensitized solar cells (DSCs). The optical and electrochemical properties of BD have been characterized using UV-vis spectroscopy and cyclic voltammetry. DSCs containing co-sensitizers, N719 and BD, have been prepared in two procedures using co-deposition and stepwise deposition. The influences of the staining processes, co-deposition and stepwise deposition on dye loading, dye dispersion on a TiO2 photoanode and DSC performance have been investigated using FTIR, SEM-EDS, I-V test and IPCE measurement, respectively. We found that stepwise co-sensitization provided higher solar cell efficiency, compared to those stained with a co-deposition method. N719/5% BD showed the highest power conversion efficiency of 5.14%. Interestingly, the enhanced device efficiency was 66% higher than that of a device containing the single N719 dye.
机译:硼双甲烯(Bodipy)以Triphenylamine Triads,BD为特色,已被合成为染料敏化太阳能电池(DSCs)的共敏化剂。 BD的光学和电化学特性已经使用UV-Vis光谱和循环伏安法表征。 使用共沉积和逐步沉积的两种方法制备含有共敏液,N719和BD的DSC。 使用FTIR,SEMEDS,I-V测试和IPCE测量,研究了染色过程,共沉积和逐步沉积对染料负载的影响,对TiO2光电阳极和DSC性能进行了影响。 与用共沉积方法染色的那些相比,我们发现逐步共敏化提供了更高的太阳能电池效率。 N719 / 5%BD显示最高功率转换效率为5.14%。 有趣的是,增强的器件效率高于包含单个N719染料的装置的66%。

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  • 来源
    《RSC Advances》 |2018年第17期|共9页
  • 作者单位

    King Mongkuts Univ Technol Thonburi Sch Energy Environm &

    Mat Div Mat Technol Bangkok 10140 Thailand;

    King Mongkuts Univ Technol Thonburi Sch Energy Environm &

    Mat Div Mat Technol Bangkok 10140 Thailand;

    King Mongkuts Univ Technol Thonburi Sch Energy Environm &

    Mat Div Mat Technol Bangkok 10140 Thailand;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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