Bis-phenylethynyl polyhedral oligomeric silsesquioxanes: new high-temperature, processable thermosetting materials

Moore Levi M. J.; Zavala Jacob J.; Lamb Jason T.; Reams Josiah T.; Yandek Gregory R.; Guenthner Andrew J.; Haddad Timothy S.; Ghiassi Kamran B.

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Bis-phenylethynyl polyhedral oligomeric silsesquioxanes: new high-temperature, processable thermosetting materials

机译：双苯基乙炔基多面体低聚倍增液氧化碳：新型高温，加工热固性材料

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Bis-phenylethynyl polyhedral oligomeric silsesquioxane (bis-PE-POSS) compounds were synthesized and thermally cured yielding crosslinked materials. After curing at 370 degrees C, thermal decomposition occurs near 600 degrees C under nitrogen. These materials were synthesized by condensation of a new phenylethynyl-functional dichlorosilane onto tetrasilanol phenyl POSS, yielding two geometric isomers.

机译：合成和热固化的双苯基乙炔基多溴硅氧烷（BIS-PEPS）化合物，得到的产物交联物质。在370℃下固化后，在氮气下发生热分解在600摄氏度附近。这些材料通过将新的苯基乙炔基官能二氯硅烷缩合到四硅醇苯基上，得到两个几何异构体。

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《RSC Advances》 |2018年第48期|共6页
作者
Moore Levi M. J.; Zavala Jacob J.; Lamb Jason T.; Reams Josiah T.; Yandek Gregory R.; Guenthner Andrew J.; Haddad Timothy S.; Ghiassi Kamran B.;
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US Air Force Res Lab Aerosp Syst Directorate Edwards Afb CA 93524 USA;

ERC Inc Edwards Afb CA 93524 USA;

ERC Inc Edwards Afb CA 93524 USA;

ERC Inc Edwards Afb CA 93524 USA;

US Air Force Res Lab Aerosp Syst Directorate Edwards Afb CA 93524 USA;

US Air Force Res Lab Aerosp Syst Directorate Edwards Afb CA 93524 USA;

ERC Inc Edwards Afb CA 93524 USA;

US Air Force Res Lab Aerosp Syst Directorate Edwards Afb CA 93524 USA;

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正文语种 eng
中图分类化学;
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1. Bis-phenylethynyl polyhedral oligomeric silsesquioxanes: new high-temperature, processable thermosetting materials [J] . Moore Levi M. J., Zavala Jacob J., Lamb Jason T., RSC Advances . 2018,第48期

机译：双苯基乙炔基多面体低聚倍增液氧化碳：新型高温，加工热固性材料
2. Sol-gel processing of polyhedral oligomeric silsesquioxanes: nanohybrid materials incorporating T-8 and T-10 cages [J] . Laird M., Yokoyama J., Carcel C., Journal of Sol-Gel Science and Technology . 2020,第3期

机译：多面体低聚倍增溶胶的溶胶 - 凝胶加工：纳入纳米用材料，包括T-8和T-10笼
3. Synthesis of 3,13-diglycidyloxypropyloctaphenyl double-decker polyhedral oligomeric silsesquioxane and the thermal reaction properties with thermosetting phenol-formaldehyde resin [J] . Niu Zhaoqi, Tian Dan, Yan Long, Journal of Applied Polymer Science . 2020,第43a44期

机译：合成3,13-二甲基氧基丙基辛基二层多面体低聚倍半硅氧烷及热反应性能与热固性酚醛树脂
4. NANOSTRUCTURED POLYHEDRAL OLIGOMERIC SILSESQUIOXANE (POSS) MOLECULES ENHANCED THERMOSETTING MATERIALS [C] . Bruce X. Fu, Chris DeArmitt, Joseph Schwab International Baltimore SAMPE Symposium and Exhibition . 2009

机译：纳米结构多面体低聚Silsesquio烷（POSS）分子增强热固性材料
5. Electronic Properties and Charge Transport of Polyhedral Oligomeric Silsesquioxanes (POSS) Derivatives and Materials Design for Highly Efficient Organic Light Emitting Diodes. [D] . Zhen, Changgua. 2011

机译：多面体低聚倍半硅氧烷（POSS）衍生物的电子性能和电荷传输以及高效有机发光二极管的材料设计。
6. Multifunctional Polyhedral Oligomeric Silsesquioxane (POSS) Based Hybrid Porous Materials for CO [O] . Mohamed Gamal Mohamed, Mei-Yin Tsai, Chih-Feng Wang, 2021

机译：多功能多面体低聚倍半硅氧烷（POSS）基于CO的杂种多孔材料
7. Bis-phenylethynyl polyhedral oligomeric silsesquioxanes: new high-temperature, processable thermosetting materials [O] . Levi M. J. Moore, Jacob J. Zavala, Jason T. Lamb, 2018

机译：双苯基乙炔基多面体低聚倍增液氧化碳：新型高温，加工热固性材料
8. Synthesis of Aromatic Polyhedral Oligomeric Silsesquioxane (POSS) Dianilines for Use in High-Temperature Polyimides. [R] . Vij, V., Haddad, T. S., Yandek, G. R., 2012

机译：用于高温聚酰亚胺的芳族多面体低聚倍半硅氧烷（pOss）二苯胺的合成。

Bis-phenylethynyl polyhedral oligomeric silsesquioxanes: new high-temperature, processable thermosetting materials

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