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首页> 外文期刊>RSC Advances >Computational investigations of click-derived 1,2,3-triazoles as keystone ligands for complexation with transition metals: a review
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Computational investigations of click-derived 1,2,3-triazoles as keystone ligands for complexation with transition metals: a review

机译：点击衍生的1,2,3-Tri zoles的计算调查作为梯形配体，用于与过渡金属融合：审查

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摘要

In recent years, metal complexes of organo 1,2,3-triazole click-derived ligands have attracted significant attention as catalysts in many chemical transformations and also as biological and pharmaceutical active agents. Regarding the important applications of these metal-organo 1,2,3-triazole-based complexes, in this review, we focused on the recently reported investigations of the structural, electronic, and spectroscopic aspects of the complexation process in transition metal complexes of 1,2,3-triazole-based click ligands. In line with this, the coordination properties of these triazole-based click ligands with transition metals were studied via several quantum chemistry calculations. Moreover, considering the complexation process, we have presented comparative discussions between the computational results and the available experimental data.
机译：近年来，有机1,2,3-三氮杂咔哒咔哒配体的金属配合物在许多化学转化中吸引了催化剂的显着关注，也是生物和药物活性剂。 关于这些金属有机体1,2,3-三唑基复合物的重要应用，在本综述中，我们专注于最近报道的结构，电子和光谱方面的过渡金属配合物的络合过程的结构，电子和光谱方面的研究 ，基于2,3-三佐盂的单击配体。 符合这一点，通过几种量子化学计算研究了基于三唑的基于点击配体的配位性能。 此外，考虑到梳理过程，我们在计算结果和可用的实验数据之间提出了比较讨论。

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