• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>RSC Advances >An enzyme-like imprinted-polymer reactor with segregated quantum confinements for a tandem catalyst
【24h】

An enzyme-like imprinted-polymer reactor with segregated quantum confinements for a tandem catalyst

机译：一种酶样印版的压印聚合物反应器，具有串联催化剂的隔离量子约束

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

This study was aimed at addressing the present challenge in tandem catalysts, as to how to furnish catalysts with tandem catalytic-ability without involving the precise control and man-made isolation of different types of catalytic sites. This objective was realized by constructing an enzyme-like imprinted-polymer reactor made of a unique polymer composite inspired from the compartmentalization of cells, a composite of a reactive imprinted polymer (containing acidic catalytic sites), and encapsulated metal nanoparticles (acting as catalytic reduction sites). The compilation of two types of catalytic sites with admissible access allowed this reactor to behave like compartments of cells for enzymatic reactions and hence catalytically constituted two quantum interaction-segregated domains, which led to the occurrence of catalytic tandem processes. Unlike the reported functional reactors that run tandem catalysis by largely depending on the precise control and man-made isolation of different types of catalytic sites, tandem catalysis in this reactor run naturally with segregated quantum confinements, which does not involve the precise control and isolation of different types of catalytic sites. This protocol presents new opportunities for the development of functional catalysts for complicated chemical processes.
机译：本研究旨在解决串联催化剂的目前挑战，以及如何用串联催化 - 能力提供催化剂，而不涉及不同类型的催化位点的精确控制和人造分离。该目的通过构建由电池独特的聚合物复合材料制成的酶样印迹 - 聚合物反应器，由电池的划分化，反应性压印聚合物（含酸性催化位点）和包封的金属纳米颗粒的复合物（用作催化还原）来实现网站）。两种类型的催化位点的汇编具有可允许的进入允许该反应器表现出酶促反应的细胞隔室，因此催化构成了两个量子相互作用分离结构域，其导致催化串联方法的发生。与报告的功能反应堆不同，通过在很大程度上根据不同类型的催化位点的精确控制和人造分离，在该反应器中的串联催化自然地具有隔离量子限制，这不涉及精确的控制和分离不同类型的催化位点。本协议为复杂化学过程的功能催化剂发育了新的机会。

著录项

  • 来源
    《RSC Advances》 |2018年第3期|共11页
  • 作者

    Wei Wenjing; Zhou Tingting; Wu Shuping; Shen Xiaojuan; Zhu Maiyong; Li Songjun;

  • 作者单位

    Jiangsu Univ Sch Mat Sci &

    Engn Inst Polymer Mat Zhenjiang 212013 Peoples R China;

    Jiangsu Univ Sch Mat Sci &

    Engn Inst Polymer Mat Zhenjiang 212013 Peoples R China;

    Jiangsu Univ Sch Mat Sci &

    Engn Inst Polymer Mat Zhenjiang 212013 Peoples R China;

    Jiangsu Univ Sch Mat Sci &

    Engn Inst Polymer Mat Zhenjiang 212013 Peoples R China;

    Jiangsu Univ Sch Mat Sci &

    Engn Inst Polymer Mat Zhenjiang 212013 Peoples R China;

    Jiangsu Univ Sch Mat Sci &

    Engn Inst Polymer Mat Zhenjiang 212013 Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号