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The hydrothermal synthesis of ultra-high aspect ratio Ag nanoflakes and their performance as conductive fillers in heaters and pastes

机译:超高纵横比Ag纳米薄蛋白的水热合成及其作为加热器和糊剂的导电填料的性能

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摘要

Ag nanoflakes with a size ranging from 5 to 60 m, a thickness of several tens of nanometers and an aspect ratio of up to 800 have been synthesized via a hydrothermal method. PVP was used as both a surfactant, inducing anisotropic growth of the Ag nanoflakes, and as a reductant, reducing Ag+ to Ag. An Ag-oxalate complex was used as a precursor, allowing effective control of the kinetic growth of the Ag nanoflakes. Influences on the size and morphology of the Ag nanoflakes, such as H+ concentration and reaction time, were discussed and analyzed. Our method can be easily scaled up for mass production. A large interfacial contact area between the Ag nanoflakes with more electrical channels makes the Ag nanoflakes excellent conductive fillers.
机译:尺寸为5至60μm的Ag纳米薄片,通过水热法合成了几十纳米的厚度和高达800的纵横比。 PVP用作表面活性剂,诱导Ag纳米薄片的各向异性生长,作为还原剂,将Ag +降低至Ag。 将Ag-草酸酯配合物用作前体,允许有效地控制Ag纳米薄片的动力学生长。 讨论和分析了对Ag纳米薄片的大小和形态的影响和分析。 我们的方法可以很容易地扩大批量生产。 具有更多电气通道的Ag纳米薄膜之间的大型界面接触面积使AG纳米薄片优异的导电填料。

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  • 来源
    《RSC Advances》 |2018年第16期|共7页
  • 作者单位

    Chinese Acad Sci Inst Solid State Phys Anhui Key Lab Nanomat &

    Nanostruct Key Lab Mat Phys Hefei 230031 Anhui Peoples R China;

    Chinese Acad Sci Inst Solid State Phys Anhui Key Lab Nanomat &

    Nanostruct Key Lab Mat Phys Hefei 230031 Anhui Peoples R China;

    Chinese Acad Sci Inst Solid State Phys Anhui Key Lab Nanomat &

    Nanostruct Key Lab Mat Phys Hefei 230031 Anhui Peoples R China;

    Chinese Acad Sci Inst Solid State Phys Anhui Key Lab Nanomat &

    Nanostruct Key Lab Mat Phys Hefei 230031 Anhui Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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