Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation

Wang Yiheng; Li Zhen Hua; Wang Huadong

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Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation

机译：氧连接发芽令人沮丧的Lewis对的合成及其在小分子活化中的应用

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Reaction of Mes(2)P(O)Li with (C6F5)(2)BCl gave access to an oxygen-linked germinal intramolecular frustrated Lewis pair Mes(2)P(O)B(C6F5)(2) (1). Compound 1 is stable at room temperature and only decomposes when heated to 90 degrees C. NMR analysis and theoretical analysis revealed the frustrated nature between the boron and phosphorus centers. Compound 1 shows typical frustrated Lewis pair reactivity when treated with dihydrogen, carbon dioxide, alkyne and alkene. The reaction of 1 with isoprene resulted in selective formation of 3,4-phosphoryl/boryl addition product 8.

机译：MES（2）P（O）Li的反应（C6F5）（2）BCL获得氧连接的发芽分子内令人沮丧的路易斯对MES（2）P（O）B（C6F5）（2）（1）。化合物1在室温下稳定，仅在加热至90摄氏度时分解。NMR分析和理论分析揭示了硼和磷中心之间的沮丧性质。化合物1显示用二氢，二氧化碳，炔烃和烯烃处理时典型的令人沮丧的Lewis对反应性。用异戊二烯的1的反应导致3,4-磷/硼酸加成产物8的选择性形成。

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《RSC Advances》 |2018年第46期|共6页
作者
Wang Yiheng; Li Zhen Hua; Wang Huadong;
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Fudan Univ Dept Chem Songhu Rd 2005 Shanghai 200438 Peoples R China;

Fudan Univ Dept Chem Songhu Rd 2005 Shanghai 200438 Peoples R China;

Fudan Univ Dept Chem Songhu Rd 2005 Shanghai 200438 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation [J] . Wang Yiheng, Li Zhen Hua, Wang Huadong RSC Advances . 2018,第46期

机译：氧连接发芽令人沮丧的Lewis对的合成及其在小分子活化中的应用
2. Frustrated Lewis Pairs beyond the Main Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene-Phosphinoaryloxide Complexes [J] . Andy M. Chapman, Mairi F. Haddow, Duncan F. Wass Journal of the American Chemical Society . 2011,第45期

机译：沮丧的路易斯对超越了主要的组：合成，反应性和阳离子茂锆-氧化膦芳基氧化物配合物的小分子活化。
3. Implications of CO2 Activation by Frustrated Lewis Pairs in the Catalytic Hydroboration of CO2: A View Using N/Si+ Frustrated Lewis Pairs [J] . von Wolff N., Lefevre G., Berthet J. -C., ACS catalysis . 2016,第7期

机译：沮丧的路易斯对活化CO2的含义在CO2催化氢硼化中的作用：使用N / Si +沮丧的路易斯对的观点
4. Synthesis of new Nitrogen/Brane frustrated Lewis pair(FLP) with a triaryl benzene framework [C] . Yuta Nakajo, Toshi Nagata 日本化学会春季年会講演予稿集 . 2018

机译：用三芳基苯框架合成新的氮/布兰特沮丧的刘易斯对（FLP）
5. "Frustrated" Lewis Pairs: Applications in olefin polymerization and small molecule activation. [D] . McCahill, Jenny Sara Jean. 2008

机译：“沮丧的”路易斯对：在烯烃聚合和小分子活化中的应用。
6. Ambiphilic Frustrated Lewis Pair Exhibiting High Robustness and Reversible Water Activation: Towards the Metal-Free Hydrogenation of Carbon Dioxide [O] . Étienne Rochette, Marc-André Courtemanche, Alexander P. Pulis, 2015

机译：具有高鲁棒性和可逆水活化性的两亲性沮丧路易斯对：朝向二氧化碳的无金属氢化
7. Indirect synthesis of a pair of formal methane activation products at a phosphane/borane frustrated Lewis pair [O] . Silke Frömel, Constantin G. Daniliuc, Christoph Bannwarth, 2016

机译：间接合成磷酸磷酸磷酸盐的一对正式甲烷活化产物刘易斯对

Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation

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