A systematic study of the co-solvent effect for an all-organic redox flow battery

Wang Xiang; Xing Xueqi; Huo Yongjie; Zhao Yicheng; Li Yongdan

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A systematic study of the co-solvent effect for an all-organic redox flow battery

机译：对全有机氧化还原电池的共溶剂效应的系统研究

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Benzophenone and 1,4-di-tert-butyl-2,5-dimethoxybenzene are used as the anode and cathode active species respectively in an all-organic redox-flow battery. A number of organics as the co-solvents are applied in the electrolyte to improve the electrochemical performance of it. For all kinds of the mixed solvents, a lower content of acetonitrile leads to a higher solubility to 1,4-di-tert-butyl-2,5-dimethoxybenzene and a lower conductivity. The results of cyclic voltammetry tests demonstrate that the electrode reactions are controlled by diffusion. With the decrease of the content of acetonitrile, the dynamic viscosity of the electrolyte increases, which generally leads to the decrease of the diffusion coefficients of the active species.

机译：二苯甲酮和1,4-二叔丁基-2,5-二甲氧基苯分别用作全有机氧化还原电池中的阳极和阴极活性物质。作为共溶剂的许多有机物施用于电解质中以改善其电化学性能。对于各种混合溶剂，乙腈的较低含量导致较高的溶解度至1,4-二叔丁基-2,5-二甲氧基苯和较低的导电性。循环伏安测定的结果表明电极反应是通过扩散控制的。随着乙腈含量的降低，电解质的动态粘度增加，这通常导致活性物质的扩散系数的降低。

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来源
《RSC Advances》 |2018年第43期|共6页
作者
Wang Xiang; Xing Xueqi; Huo Yongjie; Zhao Yicheng; Li Yongdan;
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作者单位

Tianjin Univ State Key Lab Chem Engn Tianjin Key Lab Appl Catalysis Sci &

Technol Sch Chem Engn &

Technol Tianjin 300072 Peoples R China;

Tianjin Univ State Key Lab Chem Engn Tianjin Key Lab Appl Catalysis Sci &

Technol Sch Chem Engn &

Technol Tianjin 300072 Peoples R China;

Tianjin Univ State Key Lab Chem Engn Tianjin Key Lab Appl Catalysis Sci &

Technol Sch Chem Engn &

Technol Tianjin 300072 Peoples R China;

Tianjin Univ State Key Lab Chem Engn Tianjin Key Lab Appl Catalysis Sci &

Technol Sch Chem Engn &

Technol Tianjin 300072 Peoples R China;

Tianjin Univ State Key Lab Chem Engn Tianjin Key Lab Appl Catalysis Sci &

Technol Sch Chem Engn &

Technol Tianjin 300072 Peoples R China;

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正文语种 eng
中图分类化学;
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1. A systematic study of the co-solvent effect for an all-organic redox flow battery [J] . Wang Xiang, Xing Xueqi, Huo Yongjie, RSC Advances . 2018,第43期

机译：对全有机氧化还原电池的共溶剂效应的系统研究
2. Study of Tetraethylammonium bis(trifluoromethylsulfonyl)imide as a Supporting Electrolyte for an All-organic Redox Flow Battery Using Benzophenone and 1,4-di-tert-butyl-2,5-dimethoxybenzene as Active Species [J] . Xiang Wang, Xueqi Xing, Yongjie Huo, International Journal of Electrochemical Science . 2018,第7期

机译：以二苯甲酮和1,4-二叔丁基-2,5-二甲氧基苯为活性物质的全有机氧化还原液流电池用四乙铵双（三氟甲基磺酰基）酰亚胺的研究
3. Study of Tetraethylammonium bis(trifluoromethylsulfonyl)imide as a Supporting Electrolyte for an All-organic Redox Flow Battery Using Benzophenone and 1,4-di-tert-butyl-2,5-dimethoxybenzene as Active Species [J] . Xiang Wang, Xueqi Xing, Yongjie Huo, International Journal of Electrochemical Science . 2018,第7期

机译：以二苯甲酮和1,4-二叔丁基-2,5-二甲氧基苯为活性物质的全有机氧化还原液流电池用四乙铵双（三氟甲基磺酰基）酰亚胺的研究
4. A Bispyridinylidene Anolyte for an All-Organic Redox Flow Battery [C] . Fahad Alkhayri, C. Adam Dyker Meeting of the Electrochemical Society;International Meeting on Chemical Sensors . 2020

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5. Performance and Solubility Studies of an Iron-Based Complex for Redox Flow Batteries [D] . Huyen, Huyen Thanh. 2021

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6. Systematic Study of Quaternary Ammonium Cations for Bromine Sequestering Application in High Energy Density Electrolytes for Hydrogen Bromine Redox Flow Batteries [O] . Michael Küttinger, Paulette A. Loichet Torres, Emeline Meyer, 2021

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7. Study of Tetraethylammonium bis(trifluoromethylsulfonyl)imide as a Supporting Electrolyte for an All-organic Redox Flow Battery Using Benzophenone and 1,4-di-tert-butyl-2,5-dimethoxybenzene as Active Species [O] . Xiang Wang 2018

机译：用二苯甲酸苯甲酮和1,4-二叔丁基-2,5-二甲氧基苯作为活性物种的全有机氧化还原流量的四乙基铵双（三氟甲基磺酰基）酰亚胺的研究

A systematic study of the co-solvent effect for an all-organic redox flow battery

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