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Petroleomics via Orbitrap mass spectrometry with resolving power above 1 000 000 at m/z 200

机译：通过锻体锻炼质谱法，在M / Z 200的1 000 000以上的拆分功率

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摘要

The performance of the high-field MegaOrbitrap Fourier transform mass spectrometer (FT-MS) with electrospray ionization (ESI) was evaluated to perform petroleum sample characterization via classical petroleomics approaches. Pertinent parameters that underpin the main figures of merit, that is, signal to noise ratios, dynamic range, spectral error, scan speed, mass accuracy and mass resolving power = R-p, and provide subsidies to develop these analyzers were tested. Comparisons are made with data obtained using the most common petroleomics instrument, which is a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS), that has been used in the last decade in our laboratory for crude oil analysis providing R-p of 340 000 at m/z 400 with transients of 3 s duration, and has been extensively demonstrated to fulfill all major requirements for precise petroleomics investigations. The high-field compact MegaOrbitrap mass analyzer, when operated at an R-p = 840 000 at m/z 400 (R-p 1 000 000 at m/z 200) with a detection time of 3 s, was found to be well suited for adequate characterization of crude oil. Accurate class classification and mass accuracy below 1 ppm was obtained leading to proper, comprehensive petroleomics characterization.
机译：评价高场荧光素傅立叶傅里叶傅立叶变换质谱仪（FT-MS）与电喷雾电离（ESI）的性能进行评价，以通过经典的石油源方法进行石油样本特征。基于优点的主要图形的相关参数，即信号到噪声比，动态范围，光谱误差，扫描速度，质量准确度和质量分辨率= R-P，并在测试这些分析仪进行补贴。使用最常见的石油组织仪器获得的数据进行比较，该数据是傅里叶变换离子回旋谐振质谱仪（FT-ICR MS），该质谱仪已在我们的实验室的原油分析中的最后十年中使用，提供RP为340 000在M / Z 400，具有3秒的瞬态，并且已被广泛证明，以满足精确的石油科学研究的所有主要要求。发现高场紧凑型兆疱疹质量分析仪在M / Z 400（RP＆GT;在M / Z 200）的RP = 840 000时，具有3秒的检测时间，非常适合原油的足够表征。获得准确的类别分类和低于1ppm的质量准确性，得到适当，全面的石油组织表征。

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  • 来源
    《RSC Advances》 |2018年第11期|共9页
  • 作者

    Schmidt Eduardo M.; Pudenzi Marcos A.; Santos Jandyson M.; Angolini Celio F. F.; Pereira Rosana C. L.; Rocha Ygor S.; Denisov Eduard; Damoc Eugen; Makarov Alexander; Eberlin Marcos N.;

  • 作者单位

    Univ Estadual Campinas ThoMSon Mass Spectrometry Lab Inst Chem BR-13083725 Campinas SP Brazil;

    Univ Estadual Campinas ThoMSon Mass Spectrometry Lab Inst Chem BR-13083725 Campinas SP Brazil;

    Univ Estadual Campinas ThoMSon Mass Spectrometry Lab Inst Chem BR-13083725 Campinas SP Brazil;

    Univ Estadual Campinas ThoMSon Mass Spectrometry Lab Inst Chem BR-13083725 Campinas SP Brazil;

    CENPES PETROBRAS Petr Brasileiro SA BR-21941915 Rio De Janeiro RJ Brazil;

    CENPES PETROBRAS Petr Brasileiro SA BR-21941915 Rio De Janeiro RJ Brazil;

    Thermo Fisher Sci Hanna Kunath Str 11 D-28199 Bremen Germany;

    Thermo Fisher Sci Hanna Kunath Str 11 D-28199 Bremen Germany;

    Thermo Fisher Sci Hanna Kunath Str 11 D-28199 Bremen Germany;

    Univ Estadual Campinas ThoMSon Mass Spectrometry Lab Inst Chem BR-13083725 Campinas SP Brazil;

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