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Selective modification of aligned carbon nanotubes by N-2 plasma and their diode behavior

机译:用N-2等离子体选择对准碳纳米管的选择性修饰及其二极管行为

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摘要

Aligned carbon nanotubes made by pyrolysis of ferrocene are selectively treated with N-2 plasma at various durations. Raman spectra reveal that polar bonds form at treated regions and result in increased Raman breathing mode. XPS support Raman and verify the C-O/C-N formations in carbon lattices. Electrical measurements show an unipolar p-type character as probes are placed in contact with untreated regions of nanotubes. Reposition of probes at untreated and treated regions respectively produces a current-voltage profile that resembles a p-n junction diode with forward current reaching a value as high as 100 mA at 3 V. Ab initio calculations confirm the on-tube junction and creation of a donor state is owing to C-N formations.
机译:通过在各种持续时间内用N-2等离子体选择性地处理通过热解的对准的碳纳米管。 拉曼光谱揭示了在处理区域处形成极性键,并导致拉曼呼吸模式增加。 XPS支持拉曼并验证碳格中的C-O / C-N。 电测量显示单极P型特征,因为探针与未处理的纳米管区域接触。 在未处理和处理区域处重新定位探针分别产生电流 - 电压曲线,其类似于PN结二极管,其前电流达到高达100 mA的值,在3 V. AB Initio计算证实了施主的砧座和创建施主 由于CN形成。

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  • 来源
    《RSC Advances》 |2018年第19期|共6页
  • 作者单位

    Natl Tsing Hua Univ Dept Mat Sci &

    Engn Hsinchu 30013 Taiwan;

    Natl Tsing Hua Univ Dept Mat Sci &

    Engn Hsinchu 30013 Taiwan;

    Natl Tsing Hua Univ Dept Mat Sci &

    Engn Hsinchu 30013 Taiwan;

    Natl Tsing Hua Univ Dept Mat Sci &

    Engn Hsinchu 30013 Taiwan;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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