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Far-red-emitting double-perovskite CaLaMgSbO6:Mn4+ phosphors with high photoluminescence efficiency and thermal stability for indoor plant cultivation LEDs

机译:远红发射双钙钛矿calamgsbo6:Mn4 +荧光粉具有高光致发光效率和室内植物栽培LED的热稳定性

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摘要

A series of Mn4+-activated CaLaMgSbO6 far-red-emitting phosphors were synthesized by a solid-state reaction route and the microstructure and optical characterizations were investigated in detail. Upon excitation at 370 and 469 nm, the samples showed intense far-red emission at about 708 nm originating from the E-2(g) (4)A(2g) transition and the optimal Mn4+ concentration was 0.7 mol%. The as-prepared phosphors also exhibited excellent internal quantum efficiency (88%) and high thermal stability. The emission intensity at room temperature dropped to 54% when the temperature rose to 423 K and the activation energy was 0.34 eV. The outstanding optical properties and the fact that the emission band of the obtained phosphors had a broad overlap with the absorption band of phytochrome P-FR demonstrated that the CaLaMgSbO6:Mn4+ phosphors may be promising potential spectral converters for applying to indoor plant cultivation light-emitting diodes.
机译:通过固态反应途径合成了一系列MN4 + -Activated Calamgsbo6远红发射磷光体,并详细研究了微观结构和光学表征。 在激发370和469nm时,样品在源自E-2(g)(4)(2g)转变的约708nm处显示出强烈的远红发射,最佳Mn4 +浓度为0.7mol%。 制备的磷光体也表现出优异的内部量子效率(88%)和高热稳定性。 当温度升至423k时,室温下的发射强度降至54%,激活能量为0.34eV。 所得荧光粉的发射带具有宽重叠的优异光学性质以及植物色度P-FR的吸收带,证明了Calamgsbo6:Mn4 +磷光体可能是希望施加到室内植物栽培发光的潜在光谱转换器 二极管。

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  • 来源
    《RSC Advances》 |2018年第55期|共7页
  • 作者单位

    Taiyuan Univ Technol Coll Phys &

    Optoelect Key Lab Adv Transducers &

    Intelligent Control Sys Minist Educ &

    Shanxi Prov Taiyuan 030024 Shanxi Peoples R China;

    Taiyuan Univ Technol Coll Phys &

    Optoelect Key Lab Adv Transducers &

    Intelligent Control Sys Minist Educ &

    Shanxi Prov Taiyuan 030024 Shanxi Peoples R China;

    Taiyuan Univ Technol Coll Phys &

    Optoelect Key Lab Adv Transducers &

    Intelligent Control Sys Minist Educ &

    Shanxi Prov Taiyuan 030024 Shanxi Peoples R China;

    Taiyuan Univ Technol Coll Phys &

    Optoelect Key Lab Adv Transducers &

    Intelligent Control Sys Minist Educ &

    Shanxi Prov Taiyuan 030024 Shanxi Peoples R China;

    Taiyuan Univ Technol Coll Phys &

    Optoelect Key Lab Adv Transducers &

    Intelligent Control Sys Minist Educ &

    Shanxi Prov Taiyuan 030024 Shanxi Peoples R China;

    Taiyuan Univ Technol Coll Phys &

    Optoelect Key Lab Adv Transducers &

    Intelligent Control Sys Minist Educ &

    Shanxi Prov Taiyuan 030024 Shanxi Peoples R China;

    Taiyuan Univ Technol Coll Phys &

    Optoelect Key Lab Adv Transducers &

    Intelligent Control Sys Minist Educ &

    Shanxi Prov Taiyuan 030024 Shanxi Peoples R China;

    Taiyuan Univ Technol Coll Phys &

    Optoelect Key Lab Adv Transducers &

    Intelligent Control Sys Minist Educ &

    Shanxi Prov Taiyuan 030024 Shanxi Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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