Quantitative syntheses of permethylated closo-1,10-R2C2B8Me8 (R = H, Me) carboranes. Egg-shaped hydrocarbons on the Frontier between inorganic and organic chemistry

Bakardjiev Mario; Tok Oleg L.; Ruzicka Ales; Ruzickova Zdenka; Holub Josef; Hnyk Drahomir; Fanfrlik Jindrich; Stibr Bohumil

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Quantitative syntheses of permethylated closo-1,10-R2C2B8Me8 (R = H, Me) carboranes. Egg-shaped hydrocarbons on the Frontier between inorganic and organic chemistry

机译：渗透甲基化型号为1,10-R2C2B8ME8（R = H，ME）碳硼烷的定量合成。在无机和有机化学之间的边境的蛋形碳氢化合物

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Electrophilic methylation of the closo-1,10-R2C2B8H8 (1) (R = H or Me) dicarbaboranes at higher temperatures or thermal rearrangement of the 1,6-R2C2B8Me8 (3) compounds at 400-500 degrees C generated the B-permethylated derivatives closo-1,10-R2C2B8Me8 (2) in quantitative (95%) yields. The compounds exhibit extreme air stability as a consequence of a rigid, egg shaped hydrocarbon structures incorporating inner 1,10-C2B8 carborane core.

机译：在400-500℃的较高温度或较高温度或热重排的较高温度下或热重排的二碳硼酸盐的电泳甲基化在400-500℃下产生的B-PEPTHEDALDED的较高温度或热重排。产生B-PEPTHEDATED的1,6-R2C2B8ME8（3）化合物。衍生物在定量（＆ 95％）产量中的衍生物-1,10-r2c2b8me8（2）。由于掺入内部1,10-C2B8碳磺烷芯的刚性，蛋形烃结构的后果，化合物表现出极端的空气稳定性。

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《RSC Advances》 |2018年第67期|共7页
作者
Bakardjiev Mario; Tok Oleg L.; Ruzicka Ales; Ruzickova Zdenka; Holub Josef; Hnyk Drahomir; Fanfrlik Jindrich; Stibr Bohumil;
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Acad Sci Czech Republ Inst Inorgan Chem Husinec Rez 1001 Czech Republic;

Acad Sci Czech Republ Inst Inorgan Chem Husinec Rez 1001 Czech Republic;

Univ Pardubice Fac Chem Technol Dept Gen &

Inorgan Chem Studentska 573 Pardubice 53210 Czech Republic;

Univ Pardubice Fac Chem Technol Dept Gen &

Inorgan Chem Studentska 573 Pardubice 53210 Czech Republic;

Acad Sci Czech Republ Inst Inorgan Chem Husinec Rez 1001 Czech Republic;

Acad Sci Czech Republ Inst Inorgan Chem Husinec Rez 1001 Czech Republic;

Czech Acad Sci Inst Organ Chem &

Biochem Flemingovo Nam 2 Prague 16610 6 Czech Republic;

Acad Sci Czech Republ Inst Inorgan Chem Husinec Rez 1001 Czech Republic;

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正文语种 eng
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1. Quantitative syntheses of permethylated closo-1,10-R2C2B8Me8 (R = H, Me) carboranes. Egg-shaped hydrocarbons on the Frontier between inorganic and organic chemistry [J] . Bakardjiev Mario, Tok Oleg L., Ruzicka Ales, RSC Advances . 2018,第67期

机译：渗透甲基化型号为1,10-R2C2B8ME8（R = H，ME）碳硼烷的定量合成。在无机和有机化学之间的边境的蛋形碳氢化合物
2. Ifrared and Raman Spectra of Inorganic and Coordination Compounds. Part A: Theory and Applications in Inorganic Chemistry; Part B:Application in Coordination, Organometallic, and Bioinorganic Chemistry, 5th Edition [J] . Kazuo Nakamoto Journal of Chemical Education . 2000,第9期

机译：无机和配位化合物的Ifrared和拉曼光谱。 A部分：无机化学的理论与应用; B部分：在配位，有机金属和生物无机化学中的应用，第5版
3. Outstanding Reviewers for Inorganic Chemistry Frontiers in 2017 [J] . Biswas Kanishka, Horike Satoshi, Lan Ya-Qian, Inorganic Chemistry Frontiers . 2018,第5期

机译：2017年无机化学边界的优秀审稿人
4. Syntheses and Luminescent Behavior of π-Extended Ru(bpy)_3~(2+) Derivatives through Triple Hydrogen Bonds as an Organic-inorganic Hybridized Material [C] . T. Ozawa, Y. Kishi, K. Miyamoto, Asian International Conference on Advanced Materials . 2006

机译：通过三重氢键作为有机 - 无机杂交材料的π - 延伸的Ru（BPY）_3〜（2+）衍生物的合成和发光行为
5. THE SURFACE CHEMISTRY OF LARGE HYDROCARBON AND SMALL INORGANIC MOLECULES ON OSMIUM(001) AND RUTHENIUM(001). [D] . SHANAHAN, KIRK LEO. 1984

机译：OS（001）和R（001）上大烃和小无机分子的表面化学
6. Bioinorganic Chemistry Special Feature: At the interface of inorganic chemistry and biology [O] . Jack Halpern, Kenneth N. Raymond 2003

机译：生物无机化学的特色：在无机化学和生物学的交汇处
7. (1) Nucleic Acids: their Chemical Properties and Physiological Conduct (2) The Simpler Natural Bases (3) The Chemistry of the Radio-Elements (4) Encyclopédie de Science Chimique Appliquée (5) The Principles of Inorganic Chemistry (6) The Chemistry of Cyanogen Compounds and their Manufacture and Estimation (7) Advanced Inorganic Chemistry (8) Preparations and Exercises in Inorganic Chemistry (9) A Manual of Chemistry: Theoretical and Practical, Inorganic and Organic [O] . T. M. L. 1915

机译：（1）核酸：其化学性质和生理行为（2）更简单的自然基地（3）无线电元素（4）Concyclopédiede科学ChimiqueAppliquée（5）无机化学原则（6）化学氰化合物及其制造和估计（7）晚期无机化学（8）无机化学制剂和锻炼（9）化学手册：理论实用，无机和有机

Quantitative syntheses of permethylated closo-1,10-R2C2B8Me8 (R = H, Me) carboranes. Egg-shaped hydrocarbons on the Frontier between inorganic and organic chemistry

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