Iodine-promoted stereoselective amidosulfenylation of electron-deficient alkynes

Xiao Fuhong; Wang Dahan; Yuan Shanshan; Huang Huawen; Deng Guo-Jun

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Iodine-promoted stereoselective amidosulfenylation of electron-deficient alkynes

机译：碘促进亚苯胺磺酰化的电子缺陷alkynes

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Iodine-promoted three-component synthesis of substituted -amino sulfides has been developed starting from a propargyl ester, aliphatic secondary amine, and disulfide. This protocol provides a step-economic and highly regioselective entry to trisubstituted olefins with good substrate scope and functional group tolerance.

机译：从丙基酯，脂族仲胺和二硫化物开始，碘促进了取代的 - 氨基硫化物的三组分合成。该方案为具有良好的底物范围和官能团耐受性的三取代烯烃提供了阶段经济和高度区域进入。

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《RSC Advances》 |2018年第41期|共4页
作者
Xiao Fuhong; Wang Dahan; Yuan Shanshan; Huang Huawen; Deng Guo-Jun;
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作者单位

Xiangtan Univ Key Lab Green Organ Synth &

Applicat Hunan Prov Key Lab Environm Friendly Chem &

Applicat Minist Educ Coll Chem Xiangtan 411105 Peoples R China;

Xiangtan Univ Key Lab Green Organ Synth &

Applicat Hunan Prov Key Lab Environm Friendly Chem &

Applicat Minist Educ Coll Chem Xiangtan 411105 Peoples R China;

Xiangtan Univ Key Lab Green Organ Synth &

Applicat Hunan Prov Key Lab Environm Friendly Chem &

Applicat Minist Educ Coll Chem Xiangtan 411105 Peoples R China;

Xiangtan Univ Key Lab Green Organ Synth &

Applicat Hunan Prov Key Lab Environm Friendly Chem &

Applicat Minist Educ Coll Chem Xiangtan 411105 Peoples R China;

Xiangtan Univ Key Lab Green Organ Synth &

Applicat Hunan Prov Key Lab Environm Friendly Chem &

Applicat Minist Educ Coll Chem Xiangtan 411105 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Iodine-promoted stereoselective amidosulfenylation of electron-deficient alkynes [J] . Xiao Fuhong, Wang Dahan, Yuan Shanshan, RSC Advances . 2018,第41期

机译：碘促进亚苯胺磺酰化的电子缺陷alkynes
2. Green H2O-Promoted Solvent-Free Synthesis of Enaminocarbonyl Compounds with High Stereoselectivity from Electron-Deficient Terminal Alkynes [J] . Chen Xiao Yun, Zhang Luming, Tang Yaonan, Synlett . 2020,第9期

机译：Green H 2O-促进的无溶剂合成烯氨基羰基化合物，来自电子缺陷末端alkynes具有高立体化胶合剂
3. Regio- and stereoselective reaction of 3-fluoropyridine, electron-deficient alkynes and bis(fluoroalkyl) phosphites: Catalyst- and solvent-free synthesis of polyfluoroalkylphosphonylated 3-fluoro-1,2-dihydropyridines [J] . Arbuzova Svetlana N., Gusarova Nina K., Kazantseva Tatyana I., Journal of Fluorine Chemistry . 2018,第期

机译：3-氟吡啶，电子缺乏炔烃和双（氟代烷基）亚磷酸酯的测定和立体选择反应：催化剂和无溶剂合成聚氟烷基膦基化的3-氟-1,2-二氢吡啶
4. Nickel-Catalyzed Three-Component 3 + 2 + 2 Cycloaddition of Electron-Deficient Alkylidenecyclopropanes and Two Different Alkynes [C] . Shinsuke Komagawa, Shinichi Saito Symposium on Organometallic Chemistry . 2006

机译：镍催化的三分组分3 + 2 + 2环加成电子缺乏烷基羰基丙烷和两种不同的炔烃
5. Synthesis of dienylfurans and their reactions with electron-deficient alkynes [D] . Wiget, Paul A. 2010

机译：二烯基呋喃的合成及其与缺电子炔烃的反应
6. Three-component synthesis of C2F5-substituted pyrazoles from C2F5CH2NH2·HCl NaNO2 and electron-deficient alkynes [O] . Pavel K Mykhailiuk 2015

机译：由C2F5CH2NH2·HClNaNO2和缺电子炔烃三组分合成C2F5取代的吡唑
7. Gold-Catalyzed Hydrofluorination of Electron-Deficient Alkynes: Stereoselective Synthesis of β-Fluoro Michael Acceptors [O] . Thomas J. O’Connor, F. Dean Toste 2018

机译：金催化的电子缺陷型醇化氢化氢：β-氟迈克尔受体的立体选择合成

Iodine-promoted stereoselective amidosulfenylation of electron-deficient alkynes

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