Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide

Liu Hai-Bo; Han He-Song; Lan Bin; Xiao Dong-Mei; Liang Jing; Zhang Zi-Ying; Wang Jing

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Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide

机译：基于钴金属混合有机复合物的杂化微材料：氰化物的比例检测

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A micrometer-sized hybrid crystalline material was facilely fabricated from the synergistic coordination chemistry of two types of 2-hydroxyazobenzene building blocks and cobalt ions. This hybrid crystalline material functioned as both receptor and signal reporter in cyanide (CN-) sensing with ratiometric absorption responses at 456 nm and 537 nm. The mechanism of CN- sensing involves partial ligand dissociation accompanied by the formation of a new organic metal-CN- adduct. We believe that this protocol would be valuable in achieving the expected selectivities and sensitivities for a wide variety of analytes in many chemical and biological systems in the future.

机译：千分尺寸的杂交晶体材料均由两种类型的2-羟基唑基构建块和钴离子的协同配位化学制造。该杂化结晶材料作为受体和信号报告称为氰化物（CN-）感测，在456nm和537nm处具有比率吸收响应。 CN-感测的机理涉及部分配体解离，伴随着形成新的有机金属-CN-加合物的形成。我们认为，本协议在未来在许多化学和生物系统中实现各种分析物的预期选择性和敏感性是有价值的。

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《RSC Advances》 |2018年第9期|共5页
作者
Liu Hai-Bo; Han He-Song; Lan Bin; Xiao Dong-Mei; Liang Jing; Zhang Zi-Ying; Wang Jing;
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Guangxi Univ Sch Chem &

Chem Engn Nanning 530004 Peoples R China;

Guangxi Univ Sch Chem &

Chem Engn Nanning 530004 Peoples R China;

Guangxi Univ Sch Chem &

Chem Engn Nanning 530004 Peoples R China;

Guangxi Univ Sch Chem &

Chem Engn Nanning 530004 Peoples R China;

Guangxi Univ Sch Chem &

Chem Engn Nanning 530004 Peoples R China;

Guangxi Univ Sch Chem &

Chem Engn Nanning 530004 Peoples R China;

Guangxi Univ Sch Chem &

Chem Engn Nanning 530004 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide [J] . Liu Hai-Bo, Han He-Song, Lan Bin, RSC Advances . 2018,第9期

机译：基于钴金属混合有机复合物的杂化微材料：氰化物的比例检测
2. Ratiometric fluorescence detection of cyanide based on a hybrid coumarin-hemicyanine dye: the large emission shift and the high selectivity [J] . Xin Lv, Jing Liu, Yunlong Liu, Chemical Communications . 2011,第48期

机译：基于香豆素-半花菁杂化染料的氰化物比例荧光检测：发射位移大且选择性高
3. Ratiometric fluorescence detection of silver ions using thioflavin T-based organic/inorganic hybrid supraparticles [J] . Li Yan-Yun, Zhang Min, Lu Ling-Fei, The Analyst: The Analytical Journal of the Royal Society of Chemistry: A Monthly International Publication Dealing with All Branches of Analytical Chemistry . 2015,第17期

机译：使用基于硫黄素T的有机/无机杂化超颗粒按比例荧光检测银离子
4. Hybrid Biogeography/Complex-based Optimization [C] . Chen Wang, Yang Yang International Workshop on Advanced Manufacturing and Automation . 2016

机译：混合生物地理/复杂的优化
5. Hypercoordinate silicon compounds in organic synthesis: Improved methods for the synthesis of aryl(trialkoxy)silane derivatives; and trimethylsilyl cyanide as a cyanide source for nucleophilic substitution. [D] . Manoso, Amy Slover. 2004

机译：有机合成中的超配位硅化合物：合成芳基（三烷氧基）硅烷衍生物的改进方法；三甲基甲硅烷基氰化物作为亲核取代的氰化物来源。
6. Rational Design of an ICT-Based Chemodosimeter withAggregation-Induced Emission for Colorimetric and Ratiometric FluorescentDetection of Cyanide in a Wide pH Range [O] . SachinD. Padghan, †, Li-Ching Wang, 2021

机译：基于ICT的CechodoImeter的合理设计聚集诱导的比色和比例荧光发射在宽pH范围内检测氰化物
7. Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide [O] . Hai-Bo Liu, He-Song Han, Bin Lan, 2018

机译：基于钴金属混合有机复合物的杂化微材料：氰化物的比例检测

Cobalt metal-mixed organic complex-based hybrid micromaterials: ratiometric detection of cyanide

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