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An efficient and green synthesis of ferrocenyl-quinoline conjugates via a TsOH-catalyzed three-component reaction in water

机译:通过TSOH催化的三分 - 喹啉缀合物的高效和绿色合成水中的三分组分反应

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摘要

An efficient and green synthesis of 4-ferrocenylquinoline derivatives through a TsOH-catalyzed three-component reaction of aromatic aldehydes, amines and ferrocenyl-acetylene in water has been successfully developed. This strategy is a powerful method for the construction of diverse ferrocenyl-quinoline conjugates from simple available starting materials as it minimized the use of metal catalyst and organic solvent in the reaction process. The conjugates feature unique structures and excellent electronic properties. Moreover, a plausible mechanism for this TsOH-catalyzed three-component reaction was proposed and assessed.
机译:通过TSOH催化的芳族醛,胺和胺基 - 乙炔 - 乙炔在水中有效和绿色合成4-二铁喹啉衍生物,已经成功地开发了水中的三分组分反应。 该策略是从简单的可用原料构建不同的铁茂喹啉缀合物的强大方法,因为它最小化了在反应过程中使用金属催化剂和有机溶剂。 共轭具有独特的结构和优异的电子特性。 此外,提出并评估了该TSOH催化的三分组分反应的合理机制。

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  • 来源
    《RSC Advances》 |2018年第17期|共9页
  • 作者单位

    Shandong Normal Univ Coll Chem Chem Engn &

    Mat Sci Collaborat Innovat Ctr Functionalized Probes Chem Jinan 250014 Shandong Peoples R China;

    Shandong Normal Univ Coll Chem Chem Engn &

    Mat Sci Collaborat Innovat Ctr Functionalized Probes Chem Jinan 250014 Shandong Peoples R China;

    Shandong Normal Univ Coll Chem Chem Engn &

    Mat Sci Collaborat Innovat Ctr Functionalized Probes Chem Jinan 250014 Shandong Peoples R China;

    Shandong Normal Univ Coll Chem Chem Engn &

    Mat Sci Collaborat Innovat Ctr Functionalized Probes Chem Jinan 250014 Shandong Peoples R China;

    Shandong Normal Univ Coll Chem Chem Engn &

    Mat Sci Collaborat Innovat Ctr Functionalized Probes Chem Jinan 250014 Shandong Peoples R China;

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  • 正文语种 eng
  • 中图分类 化学;
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