Nanostructural catalyst: metallophthalocyanine and carbon nano-onion with enhanced visible-light photocatalytic activity towards organic pollutants

Regulska Elzbieta; Olejnik Piotr; Zubyk Halyna; Czyrko-Horczak Justyna; Chaur Manuel N.; Tomczykowa Monika; Butsyk Olena; Brzezinski Krzysztof; Echegoyen Luis; Plonska-Brzezinska Marta E.

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Nanostructural catalyst: metallophthalocyanine and carbon nano-onion with enhanced visible-light photocatalytic activity towards organic pollutants

机译：纳米结构催化剂：金属酞菁和碳纳米洋葱，具有增强的有机污染物的可见光光催化活性

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Metallophthalocyanine (MPc) and carbon nano-onion (CNO) derivatives were synthesized and characterized by using ultraviolet-visible spectroscopy, infrared and Raman spectroscopy, scanning electron microscopy with energy-dispersive X-ray spectroscopy and X-ray powder diffraction. The unmodified CNOs and MPc-CNO derivatives were used as photocatalysts for rhodamine B (RhB) degradation under visible-light irradiation. The photocatalytic studies revealed that the MPc-CNO nanostructural materials simultaneously exhibited a high absorption capacity and an excellent visible-light-driven photocatalytic activity towards RhB. These nanostructures possess great potential for use as active photocatalysts for organic pollutant degradation.

机译：通过使用紫外线可见光谱，红外和拉曼光谱，扫描电子显微镜和X射线粉末衍射来合成金属酞菁（MPC）和碳纳米洋葱（CNO）衍生物的合成和表征。未改性的CNO和MPC-CNO衍生物被用作罗丹明B（RHB）降解在可见光照射下的光催化剂。光催化研究表明，MPC-CNO纳米结构材料同时表现出高吸收能力和朝向RHB的优异的可见光光催化活性。这些纳米结构具有很大的用途，可用作有机污染物降解的活性光催化剂。

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《RSC Advances》 |2020年第18期|共11页
作者
Regulska Elzbieta; Olejnik Piotr; Zubyk Halyna; Czyrko-Horczak Justyna; Chaur Manuel N.; Tomczykowa Monika; Butsyk Olena; Brzezinski Krzysztof; Echegoyen Luis; Plonska-Brzezinska Marta E.;
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Univ Bialystok Fac Chem Ciolkowskiego 1K PL-15245 Bialystok Poland;

Med Univ Bialystok Div Lab Med Fac Pharm Mickiewicza 2A PL-15222 Bialystok Poland;

Univ Bialystok Fac Chem Ciolkowskiego 1K PL-15245 Bialystok Poland;

Univ Bialystok Fac Chem Ciolkowskiego 1K PL-15245 Bialystok Poland;

Univ Valle Fac Ciencias Nat &

Exactas Dept Quim Cali Colombia;

Med Univ Bialystok Div Lab Med Fac Pharm Mickiewicza 2A PL-15222 Bialystok Poland;

Czech Acad Sci Inst Phys Na Slovance 2 Prague 18221 8 Czech Republic;

Univ Bialystok Fac Chem Ciolkowskiego 1K PL-15245 Bialystok Poland;

Univ Texas El Paso Dept Chem 500 W Univ Ave El Paso TX 79968 USA;

Med Univ Bialystok Div Lab Med Fac Pharm Mickiewicza 2A PL-15222 Bialystok Poland;

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1. Nanostructural catalyst: metallophthalocyanine and carbon nano-onion with enhanced visible-light photocatalytic activity towards organic pollutants [J] . Regulska Elzbieta, Olejnik Piotr, Zubyk Halyna, RSC Advances . 2020,第18期

机译：纳米结构催化剂：金属酞菁和碳纳米洋葱，具有增强的有机污染物的可见光光催化活性
2. Facile synthesis of CdS/Bi4V2O11 photocatalysts with enhanced visible-light photocatalytic activity for degradation of organic pollutants in water [J] . Lv Taotao, Li Di, Hong Yuanzhi, Dalton transactions: An international journal of inorganic chemistry . 2017,第37期

机译：Cds / Bi4V2O11光催化剂的体积合成，具有增强的可见光光催化活性，用于降解水中有机污染物的降解
3. A novel Z-scheme WO3/CdWO4 photocatalyst with enhanced visible-light photocatalytic activity for the degradation of organic pollutants [J] . Aslam Imran, Cao Chuanbao, Tanveer M., RSC Advances . 2015,第8期

机译：具有增强可见光光催化活性的新型Z型WO3 / CdWO4光催化剂用于降解有机污染物
4. Preparation of Visible-Light Responsive Photocatalyst (Bi20TiO32) and Its Photocatalytic Activity for Degrading Organic Pollutants [C] . Sun Xuhui, Sun Lin, Zhang Hongbo, Energy and Environment Technology, 2009. ICEET '09 . 2009

机译：可见光响应型光催化剂（Bi20TiO32）的制备及其对有机污染物的降解活性
5. Synthesizing Efficient Quasi-One-Dimension Titanium Dioxide Nanocatalyst for Enhanced Photocatalytic Degradation of Aqueous Organic Pollutants and Hydrogen Production [D] . Peng, Tao. 2018

机译：合成高效的准一维二氧化钛纳米催化剂，用于增强含水有机污染物和氢气生产的光催化降解
6. Novel Ternary Heterogeneous Reduction Graphene Oxide (RGO)/BiOCl/TiO2 Nanocomposites for Enhanced Adsorption and Visible-Light Induced Photocatalytic Activity toward Organic Contaminants [O] . Zhanxin Jing, Xiangyi Dai, Xueying Xian, 2020

机译：新型三元均相还原氧化石墨烯（RGO）/ BiOCl / TiO2纳米复合材料用于增强对有机污染物的吸附和可见光诱导的光催化活性
7. Enhanced visible-light photocatalytic activity and photostability of Ag3PO4/Bi2WO6 heterostructures toward organic pollutant degradation and plasmonic Z-scheme mechanism [O] . Fengyan Ma, Qilin Yang, Zhengjun Wang, 2018

机译：增强Ag3PO4 / Bi2WO6异质结构朝向有机污染物降解和等离子体Z方案机制的增强的可见光光催化活性和光稳定性

Nanostructural catalyst: metallophthalocyanine and carbon nano-onion with enhanced visible-light photocatalytic activity towards organic pollutants

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