A pH tuning single fluorescent probe based on naphthalene for dual-analytes (Mg(2+)and Al3+) and its application in cell imaging

Yu Chunwei; Cui Shuhua; Ji Yuxiang; Wen Shaobai; Jian Li; Zhang Jun

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A pH tuning single fluorescent probe based on naphthalene for dual-analytes (Mg(2+)and Al3+) and its application in cell imaging

机译：基于萘对双分析物（Mg（2+）和Al3 +）的pH调节单荧光探针及其在细胞成像中的应用

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In this study, a naphthalene Schiff-basePwhich serves as a dual-analyte probe for the quantitative detection of Al(3+)and Mg(2+)has been designed. The proposed probe showed an ''off-on'' fluorescent response toward Al(3+)in ethanol-water solution (1 : 9, v/v, pH 6.3, 20 mM HEPES) over other metal ions and anions, while the detection by the probe could be switched to Mg(2+)by regulating the pH from 6.3 to 9.4. The sensing mechanisms ofPto Al3+/Mg(2+)are attributed to inhibition of the photo-induced electron transfer (PET) process by the formation of 1 : 1 ligand-metal complexes. More importantly, the probe was applied successfully in living cells for the fluorescent cell-imaging of Al(3+)and Mg2+.

机译：在本研究中，萘席夫碱基是为Al（3+）和Mg（2+）的定量检测的双分析物探针。所提出的探针显示在其他金属离子和阴离子上的乙醇 - 水溶液（1：9，v / v，pH6.3,6.3,20mM Hepes）的“OFF上”荧光反应。通过调节6.3至9.4的pH可以通过调节pH切换到Mg（2+）的检测。 OFPTO Al3 + / mg（2+）的感测机制归因于通过形成1：1配体 - 金属配合物的形成抑制光诱导的电子转移（PET）工艺。更重要的是，探针在活细胞中成功应用于Al（3+）和Mg2 +的荧光细胞成像。

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来源
《RSC Advances》 |2020年第36期|共7页
作者
Yu Chunwei; Cui Shuhua; Ji Yuxiang; Wen Shaobai; Jian Li; Zhang Jun;
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作者单位

Hainan Med Univ Sch Trop &

Lab Med Lab Environm Monitoring Haikou 571101 Hainan Peoples R China;

Weifang Univ Sci &

Technol Shouguang 262700 Shandong Peoples R China;

Hainan Med Univ Sch Trop &

Lab Med Lab Environm Monitoring Haikou 571101 Hainan Peoples R China;

Hainan Med Univ Sch Trop &

Lab Med Lab Environm Monitoring Haikou 571101 Hainan Peoples R China;

Hainan Med Univ Sch Trop &

Lab Med Lab Environm Monitoring Haikou 571101 Hainan Peoples R China;

Hainan Med Univ Sch Trop &

Lab Med Lab Environm Monitoring Haikou 571101 Hainan Peoples R China;

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正文语种 eng
中图分类化学;
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1. A pH tuning single fluorescent probe based on naphthalene for dual-analytes (Mg(2+)and Al3+) and its application in cell imaging [J] . Yu Chunwei, Cui Shuhua, Ji Yuxiang, RSC Advances . 2020,第36期

机译：基于萘对双分析物（Mg（2+）和Al3 +）的pH调节单荧光探针及其在细胞成像中的应用
2. A naphthalene-quinoline based chemosensor for fluorescent "turn-on" and absorbance-ratiometric detection of Al3+ and its application in cells imaging [J] . Zeng Shuang, Li Shi-Jie, Sun Xue-Jiao, Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2018,第期

机译：基于荧光“开启”的萘喹啉基化学传感器和Al3 +的吸光度 - 比例检测及其在细胞成像中的应用
3. A new red fluorescent probe for Hg~(2+)based on naphthalene diimide and its application in living cells, reversibility on strip papers [J] . Luyi Zong, Yujun Xie, Qianqian Li, Sensors and Actuators . 2017,第jana期

机译：基于萘二酰亚胺的新型Hg〜（2+）红色荧光探针及其在活细胞中的应用和可逆性
4. Fluorescent water-Soluble Probes Based on Ammonium Cation Peg Substituted Perylenepisimides: Synthesis, Photophysical Properties, and Live Cell Images [C] . Wei Yang, Jiaxuan Cai, Shuchen Zhang Annual International Conference on Material Science and Environmental Engineering . 2018

机译：基于铵阳离子PEG取代的Per alenEpisides的荧光水溶性探针：合成，光药性和活细胞图像
5. Subunits of highly fluorescent protein R-phycoerythrin as probes for cell imaging and single-molecule detection. [D] . Isailovic, Dragan. 2005

机译：高荧光蛋白R-藻红蛋白的亚基，可作为细胞成像和单分子检测的探针。
6. A Benzothiazole-Based Fluorescent Probe for Ratiometric Detection of Al3+ and Its Application in Water Samples and Cell Imaging [O] . Zhen-Nan Tian, Ding-Qi Wu, Xue-Jiao Sun, 2019

机译：基于苯并噻唑的Al3 +比例检测荧光探针及其在水样和细胞成像中的应用
7. A pH tuning single fluorescent probe based on naphthalene for dual-analytes (Mg2+ and Al3+) and its application in cell imaging [O] . Chunwei Yu, Shuhua Cui, Yuxiang Ji, 2020

机译：基于萘进行双分析物（Mg2 +和Al3 +）的pH调节单荧光探针及其在细胞成像中的应用

A pH tuning single fluorescent probe based on naphthalene for dual-analytes (Mg(2+)and Al3+) and its application in cell imaging

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