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Formononetin in Radix Hedysari extract-mediated green synthesis of gold nanoparticles for colorimetric detection of ferrous ions in tap water

机译:甲基麦萨里酶的甲酰键蛋白提取物介导的金纳米颗粒的绿色合成,用于自来水中的黑色金属离子检测

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摘要

This study linked natural plant materials and nanomaterials; reporting an environmentally friendly, non-toxic and efficient method for the green synthesis of gold nanoparticles (AuNPs) using an ethyl acetate extract of Radix Hedysari (EAR). The components of the extract were identified using HPLC and it was found that formononetin accounted for more than 90% of the total contents. We predicted that formononetin in EAR plays a crucial role in green synthesis. Thus, formononetin was used as a standard reductant to synthesize AuNPs, and the result confirmed our prediction. The synthetic mechanism was also discussed in detail in the article. Moreover, EAR-AuNPs realized the sensitive and selective colorimetric detection of ferrous ions (Fe2+) among other metal ions, and were applied to spiked tap water with a low detection limit of 1.5 mu M in a wide range from 10 mu M to 500 mu M. EAR-AuNPs were green synthesized using Radix Hedysari extract for the first time and were successfully applied in real sample detection.
机译:本研究链接了天然植物材料和纳米材料;报告使用乙酸乙酸乙酸乙酸乙酯提取物(耳)的乙酸乙酯提取物进行环保,无毒,有效的糖果(AUNP)的绿色合成。使用HPLC鉴定提取物的组分,发现Formononetin占总含量的90%以上。我们预测,耳中的Formononetin在绿色合成中起着至关重要的作用。因此,用作合成AUNP的标准还原剂用作标准还原剂,结果证实了我们的预测。还在制品中详细讨论了合成机制。此外,耳罩实现了其他金属离子中的铁离子(Fe2 +)的敏感和选择性比色性检测,并施加到尖刺的自来水,检测限为1.5μm的宽范围,范围为10 mu m至500μm M.首次使用基质Hedysari提取物合成绿色的耳朵,并成功地应用于实际样品检测。

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  • 来源
    《RSC Advances》 |2020年第54期|共9页
  • 作者单位

    Lanzhou Univ Sch Pharm Inst Pharmaceut Anal Lanzhou 730000 Peoples R China;

    Lanzhou Univ Sch Pharm Inst Pharmaceut Anal Lanzhou 730000 Peoples R China;

    Lanzhou Univ Sch Pharm Inst Pharmaceut Anal Lanzhou 730000 Peoples R China;

    Lanzhou Univ Sch Pharm Inst Pharmaceut Anal Lanzhou 730000 Peoples R China;

    Lanzhou Univ Sch Pharm Inst Pharmaceut Anal Lanzhou 730000 Peoples R China;

    Lanzhou Univ Hosp 2 Lanzhou 730030 Peoples R China;

    Lanzhou Univ Sch Pharm Inst Pharmaceut Anal Lanzhou 730000 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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