Yttrium(iii) coordination polymer micro/nanospheres with single ligand and dual ligands

Ji Yanhua; Guo Qifeng; Yang Qingquan; Gao Yong; Yan Xiaojun; Liu Hongning; Zeng Zhijun

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Yttrium(iii) coordination polymer micro/nanospheres with single ligand and dual ligands

机译：YTTRIUM（III）配位聚合物微/纳米用单一配体和双配体

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In this work, yttrium(iii) coordination polymer (Y-CP) ball-flower-shaped microparticles with diameters ranging from 5 mu m to 10 mu m were synthesized using vanillin and asparagine as ligands under solvothermal conditions at 150 degrees C for 24 h. Then, we investigated the reaction influencing factors such as the concentration of reactants (involving vanillin, asparagine, and rare earth), reaction temperature, and reaction time. Both uniform and sphere-like nanoparticles with an average size of similar to 50 nm were obtained using vanillin as a ligand at 120 degrees C for 12 h. Furthermore, the products were characterized and the results of cytotoxicity research demonstrated that the nanoparticles had low cytotoxicity and the coordination polymer nanospheres were perfectly biocompatible.

机译：在这项工作中，使用Vanillin和天冬酰胺在150℃下在150℃下以150℃的溶剂和天冬酰胺来合成钇（III）配位聚合物（Y-CP）球形微粒，其直径为5μm至10μm。。然后，我们研究了反应影响因子，例如反应物的浓度（涉及香草醛，天冬酰胺和稀土），反应温度和反应时间。使用Vanillin作为配体在120℃下以120℃的12小时获得平均尺寸的均匀和球形纳米颗粒。此外，产品的特征在于，细胞毒性研究结果表明，纳米颗粒具有低细胞毒性，并且配位聚合物纳米球是完全生物相容性的。

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来源
《RSC Advances》 |2020年第54期|共6页
作者
Ji Yanhua; Guo Qifeng; Yang Qingquan; Gao Yong; Yan Xiaojun; Liu Hongning; Zeng Zhijun;
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作者单位

Univ Jiangxi TCM Nanchang 330006 Jiangxi Peoples R China;

Univ Jiangxi TCM Jiangxi Prov Key Lab TCM Etiopathogenisis Res Ctr Different &

Dev TCM Basic Theory Nanchang 330006 Jiangxi Peoples R China;

Univ Jiangxi TCM Jiangxi Prov Key Lab TCM Etiopathogenisis Res Ctr Different &

Dev TCM Basic Theory Nanchang 330006 Jiangxi Peoples R China;

Univ Jiangxi TCM Jiangxi Prov Key Lab TCM Etiopathogenisis Res Ctr Different &

Dev TCM Basic Theory Nanchang 330006 Jiangxi Peoples R China;

Univ Jiangxi TCM Jiangxi Prov Key Lab TCM Etiopathogenisis Res Ctr Different &

Dev TCM Basic Theory Nanchang 330006 Jiangxi Peoples R China;

Univ Jiangxi TCM Jiangxi Prov Key Lab TCM Etiopathogenisis Res Ctr Different &

Dev TCM Basic Theory Nanchang 330006 Jiangxi Peoples R China;

Univ Jiangxi TCM Nanchang 330006 Jiangxi Peoples R China;

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正文语种 eng
中图分类化学;
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1. Yttrium(iii) coordination polymer micro/nanospheres with single ligand and dual ligands [J] . Ji Yanhua, Guo Qifeng, Yang Qingquan, RSC Advances . 2020,第54期

机译：YTTRIUM（III）配位聚合物微/纳米用单一配体和双配体
2. New yttrium(III) and copper(II) coordination polymers with partially protonated cyclohexane-1,2,3,4,5,6-hexacarboxylato ligands: Synthesis, crystal structures and properties [J] . Zheng Y.-Q., Guo X.-X., Han X.-Y., Inorganica Chimica Acta . 2011,第1期

机译：具有部分质子化环己烷-1,2,3,4,5,6-六羧基配体的新型钇（III）和铜（II）配位聚合物：合成，晶体结构和性质
3. Adventures in the Coordination Chemistry of Di-2-pyridyl Ketone and Related Ligands: From High-Spin Molecules and Single-Molecule Magnets to Coordination Polymers, and from Structural Aesthetics to an Exciting New Reactivity Chemistry of Coordinated Ligands [J] . Stamatatos TC, Efthymiou CG, Stoumpos CC, European journal of inorganic chemistry . 2009,第23期

机译：二-2-吡啶酮和相关配体的配位化学历险记：从高旋转分子和单分子磁体到配位聚合物，从结构美学到配体的令人兴奋的新反应性化学
4. Structural and Photophysical Properties of Eu(III) Coordination Polymer with an Axial Chiral Ligand [C] . Naovuki Koiso, Yuichi Kitagawa, Takayuki Nakanishi Rare Earth Research Conference . 2019

机译：欧盟（III）配位与轴向手性配体的结构和光物理性质
5. Design and synthesis of microporous metal coordination polymers using polybenzoate ligands. [D] . Chui, Sin Yin. 1999

机译：使用聚苯甲酸酯配体设计和合成微孔金属配位聚合物。
6. Crystal structure of a mixed-ligand terbium(III) coordination polymer containing oxalate and formate ligands having a three-dimensional fcu topology [O] . Chainok Kittipong, Phailyn Khemthong, Filip Kielar, 2016

机译：含草酸酯和甲酸配体的混合配体ter（III）配位聚合物的晶体结构具有三维fcu拓扑
7. Crystal structure of a mixed-ligand terbium(III) coordination polymer containing oxalate and formate ligands, having a three-dimensional fcu topology [O] . Chainok Kittipong, Phailyn Khemthong, Filip Kielar, 2016

机译：含有草酸盐和甲酸盐配体的混合配体铽（III）配位聚合物的晶体结构，具有三维fcu拓扑结构

Yttrium(iii) coordination polymer micro/nanospheres with single ligand and dual ligands

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