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首页> 外文期刊>RSC Advances >The morphology of poly(terminal vinyl dimethicone-co-methyl methacrylate-co-n-butyl acrylate)/pigment composite film and its application in pigment printing of polyester fabric
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The morphology of poly(terminal vinyl dimethicone-co-methyl methacrylate-co-n-butyl acrylate)/pigment composite film and its application in pigment printing of polyester fabric

机译:聚(末端乙烯基二甲基硅氧烷二甲酯 - 甲基丙烯酸甲基丙烯酸甲酯 - 丙烯酸丙烯酸酯)/颜料复合膜的形态及其在聚酯织物的颜料印刷中的应用

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摘要

In this study, a series of poly(terminal vinyl dimethicone-co-methyl methacrylate-co-n-butyl acrylate)/pigment composite particles (P(DMS-Acr)/PB CPs) were successfully prepared via miniemulsion polymerization and their latex film microstructures on were examined carefully using transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM) and so on. Significant phase separation was observed after film formation, and the copper phthalocyanine blue (PB) particles tend to distribute in the polysiloxane island phase. After baking at 120 degrees C, the protrusions were generated. With increasing amount of vinyl terminated polydimethylsiloxane (ViPDMS) or baking time, the number of the protrusions became more and the appearance of the protrusions tends to be sharp. When the P(DMS-Acr)/PB CPs were applied in fabric printing, a continuous film was formed on the surface of the fabric at room temperature and therefore the gaps between yarns were blocked. However, the gaps in the fabric reappeared after baking at 120 degrees C, which could be attributed to the rapid flow of the polymer component. Finally, the fiber was coated with a layer of latex film containing a large number of mastoid structures, and the printed fabric could still retain the majority of the gaps between yarns and between fibers. Therefore, the printed fabric exhibited excellent performances such as good air permeability, softness, and rubbing fastness.
机译:在该研究中,通过微乳液聚合及其胶乳膜成功制备了一系列聚(末端乙烯基二甲基硅氧烷 - 共聚甲基丙烯酸甲基丙烯酸酯 - 丙烯酸酯)/颜料复合颗粒(P(DMS-ACR)/ PB CPS)使用透射电子显微镜(TEM),现场发射扫描电子显微镜(FeSEM),原子力显微镜(AFM)等,仔细检查微观结构。在膜形成后观察到显着的相分离,铜酞菁蓝(Pb)颗粒倾向于在聚硅氧烷岛岛中分布。在120摄氏度下烘烤后,产生突起。随着量的乙烯基封端的聚二甲基硅氧烷(VIPDM)或烘烤时间,突起的数量变得越来越多,并且突起的外观趋于尖锐。当P(DMS-ACR)/ PB CPS在织物印刷中施加时,在室温下在织物的表面上形成连续膜,因此纱线之间的间隙被封闭。然而,在120℃下烘烤后,织物中的间隙再次出现,这可能归因于聚合物组分的快速流动。最后,纤维涂有含有大量乳突结构的胶乳膜层,并且印刷织物仍然可以保留纱线和纤维之间的大部分间隙。因此,印刷织物表现出优异的性能,例如良好的透气性,柔软性和摩擦牢度。

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  • 来源
    《RSC Advances》 |2020年第9期|共7页
  • 作者单位

    Wenzhou Polytech Key Lab Surface Modificat Polymer Mat Wenzhou 325035 Peoples R China;

    Zhejiang Sci Tech Univ Key Lab Adv Text Mat &

    Mfg Technol Minist Educ Hangzhou 310018 Zhejiang Peoples R China;

    Wenzhou Polytech Key Lab Surface Modificat Polymer Mat Wenzhou 325035 Peoples R China;

    Zhejiang Sci Tech Univ Key Lab Adv Text Mat &

    Mfg Technol Minist Educ Hangzhou 310018 Zhejiang Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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