One-step-synthesizedd-gluconic acetal-based supramolecular organogelators with effective phase-selective gelation

Fan Kaiqi; Wang Xiaobo; Wang Xiao; Yang Haoran; Han Guanglu; Zhou Liming; Fang Shaoming

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One-step-synthesizedd-gluconic acetal-based supramolecular organogelators with effective phase-selective gelation

机译：基于一步合成的 - 葡萄糖缩缩超分子有机凝胶，具有有效的相位选择性凝胶化

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Two effective and one-step-synthesized organogelators based ond-gluconic acetal derivatives have been developed to show phase-selective gelation behaviours towards aromatic solvents from their biphasic mixtures with water. The dominant factors that drive gelation have been studied using FT-IR and temperature-dependent(1)H NMR spectroscopy. Particularly, gelatorGAA-2in powder form could selectively congeal toluene, benzene ando-xylene at room temperature under mild stirring. Additionally,GAA-2could gelate the aromatic solvents within 10 min and the recovery rate of the aromatic solvents could reach about 82% under a certain condition. The benefits of wide source availability, being easy to synthesize, and recyclable performance of the gelator makeGAA-2ideal for real-world remediation of aromatic solvents.

机译：已经开发了两种有效和一步合成的基于葡萄糖缩醛衍生物的有机糖剂，以显示与水的双相混合物的芳族溶剂的相选择性凝胶化行为。已经使用FT-IR和温度依赖性（1）H NMR光谱研究了驱动凝胶化的主要因素。特别地，GelatorgaA-2in粉末形式可以在温和搅拌下在室温下选择性地凝集甲苯，苯和二甲苯。另外，GaA-2在10分钟内将芳族溶剂凝胶化，并且在一定条件下芳香溶剂的回收率可达到约82％。广泛源可用性的好处，易于合成，凝胶剂Makegaa-2的可回收性能，用于真实的芳族溶剂的修复。

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《RSC Advances》 |2020年第61期|共6页
作者
Fan Kaiqi; Wang Xiaobo; Wang Xiao; Yang Haoran; Han Guanglu; Zhou Liming; Fang Shaoming;
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作者单位

Zhengzhou Univ Light Ind Coll Mat &

Chem Engn Zhengzhou 450002 Peoples R China;

Zhengzhou Univ Light Ind Journal Editorial Dept Zhengzhou 450002 Peoples R China;

Zhengzhou Univ Light Ind Coll Comp &

Commun Engn Zhengzhou 450002 Peoples R China;

Zhengzhou Univ Light Ind Coll Mat &

Chem Engn Zhengzhou 450002 Peoples R China;

Zhengzhou Univ Light Ind Coll Mat &

Chem Engn Zhengzhou 450002 Peoples R China;

Zhengzhou Univ Light Ind Coll Mat &

Chem Engn Zhengzhou 450002 Peoples R China;

Zhengzhou Univ Light Ind Coll Mat &

Chem Engn Zhengzhou 450002 Peoples R China;

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正文语种 eng
中图分类化学;
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1. One-step-synthesizedd-gluconic acetal-based supramolecular organogelators with effective phase-selective gelation [J] . Fan Kaiqi, Wang Xiaobo, Wang Xiao, RSC Advances . 2020,第61期

机译：基于一步合成的 - 葡萄糖缩缩超分子有机凝胶，具有有效的相位选择性凝胶化
2. One-step-synthesized d-gluconic acetal-based supramolecular organogelators with effective phase-selective gelation [J] . Kaiqi Fan, Xiaobo Wang, Xiao Wang, RSC Advances . 2020,第61期

机译：基于一步合成的D-葡萄糖缩缩的超分子器官，具有有效相选择性凝胶化
3. Sorbitol-based supramolecular organogelators with effective phase-selective gelation and significant self-healing property [J] . Fan Kaiqi, Ma Yongpeng, Wang Xiaobo, Soft Materials . 2018,第1a4期

机译：基于山梨糖醇的超分子有机胶凝剂，具有有效的相选择胶凝作用和显着的自愈特性
4. A Phase-Selective Supramolecular Gelator as Oil Solidifier [C] . Shaozhu Liu, Weili Liu, Zhigang Liu, International Conference on Frontiers of Mechanical Engineering and Materials Engineering . 2014

机译：作为油固化剂的相选择性超分子胶凝胶
5. Investigation of Dendrimer-reinforced PLA Composite System and Fluorescent Supramolecular Gels. [D] . Chen, Yuan. 2011

机译：树枝状聚合物增强的PLA复合体系和荧光超分子凝胶的研究。
6. Supramolecular Phase-Selective Gelation by Peptides Bearing Side-Chain Azobenzenes: Effect of Ultrasound and Potential for Dye Removal and Oil Spill Remediation [O] . Jürgen Bachl, Stefan Oehm, Judith Mayr, 2015

机译：带有侧链偶氮苯的肽的超分子相选择性凝胶化：超声和染料去除和溢油修复的潜力的影响
7. Supramolecular phase-selective gelation by peptides bearing side-chain azobenzenes: Effect of ultrasound and potential for dye removal and oil spill remediation [O] . Bachl, Jürgen, Oehm, Stefan, Mayr, Judith, 2015

机译：带有侧链偶氮苯的肽的超分子相选择性凝胶化：超声的影响以及染料去除和溢油修复的潜力

One-step-synthesizedd-gluconic acetal-based supramolecular organogelators with effective phase-selective gelation

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