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MoS42- intercalated NiFeTi LDH as an efficient and selective adsorbent for elimination of heavy metals

机译:MOS42-嵌入Nifeti LDH作为消除重金属的有效和选择性吸附剂

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摘要

The enormous increase of heavy metal pollution has led to a rise in demand for synthesizing efficient and stable adsorbents for its treatment. Therefore, we have designed a novel adsorbent by introducing (MoS4)(2-) moieties within the layers of NiFeTi LDH-NO3, via an ion exchange mechanism, as a stable and efficient adsorbent to deal with the increasing water pollution due to heavy metals. Characterization techniques such as XRD, FTIR, TGA, SEM, TEM, and Raman spectroscopy were used to confirm the formation of (MoS4)(2-) intercalated NiFeTi LDH and structural changes after the adsorption process. The efficiency of the material was tested with six heavy metal ions, among which it was found to be effective for toxic Pb2+ and Ag+ ions. When selectivity was studied with all six of the metal ions copresent in one solution, the material showed greater selectivity for Pb2+ and Ag+ ions with the selectivity order of Ni2+ < Cu2+ < Zn2+ < Fe3+ < Pb2+ < Ag+, with great adsorption capacities of 653 mg g(-1) for Pb2+ and 856 mg g(-1) for Ag+ metal ions. Further, the kinetics adsorption study for both the metal ions had a great correlation with the pseudo-second-order model and supported the chemisorption process via the formation of M-S bonding. The adsorption process obeyed the Langmuir model. Therefore, the MoS4-LDH material could be a promising adsorbent for the removal of heavy metals.
机译:重金属污染的巨大增加导致了合成有效和稳定的吸附剂的需求增加。因此,我们设计了一种通过离子交换机制引入(MOS4)(2-)部分,通过离子交换机制引入(2-)部分,作为稳定且有效的吸附剂,以处理由于重金属而增加的水污染。诸如XRD,FTIR,TGA,SEM,TEM和拉曼光谱的表征技术用于确认(MOS4)(2-)插入的尼弗提LDH和在吸附过程之后的结构变化。用六个重金属离子测试材料的效率,其中发现它是有效的PB2 +和Ag +离子的有效性。当用一种溶液中的所有六个金属离子进行选择性时,该材料对Ni2 +

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  • 来源
    《RSC Advances》 |2020年第33期|共11页
  • 作者单位

    Univ Delhi Dept Chem Drug Discover &

    Dev Lab Delhi 110007 India;

    Univ Delhi Dept Chem Drug Discover &

    Dev Lab Delhi 110007 India;

    Univ Delhi Dept Chem Drug Discover &

    Dev Lab Delhi 110007 India;

    Univ Delhi Dept Chem Drug Discover &

    Dev Lab Delhi 110007 India;

    Univ Delhi Dept Chem Drug Discover &

    Dev Lab Delhi 110007 India;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
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