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An effective utilization of MXene and its effect on electromagnetic interference shielding: flexible, free-standing and thermally conductive composite from MXene-PAT-poly(p-aminophenol)-polyaniline co-polymer

机译:MXENE的有效利用及其对电磁干扰屏蔽的影响:柔性,独立式和来自MXENE-PAT-POLY(P-氨基苯酚)的热导电复合材料 - 聚胺共聚物

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摘要

MXene and conductive polymers are attractive candidates for electromagnetic interference shielding (EMI) applications. The MXene-PAT-conductive polymer (CP) composites were fabricated by a cost-effective spray coating technique and characterized using X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), X-ray diffraction (XRD) and Raman spectroscopy. A new approach has been developed for the synthesis of exfoliated MXene. The MXene-PAT-poly(p-aminophenol)-polyaniline co-polymer composite exhibited good electric conductivity (EC) of 7.813 S cm(-1). The composites revealed an excellent thermal properties, which were 0.687 W (m K)(-1) thermal conductivity, 2.247 J (g K)(-1) heat capacity, 0.282 mm(2) s(-1) thermal diffusivity and 1.330 W s(1/2) m(-2) K-1 thermal effusivity. The composites showed 99.99% shielding efficiency and the MXene-PAT-PANI-PpAP composite (MXPATPA) had EMI shielding effectiveness of 45.18 dB at 8.2 GHz. The reduced form of MXene (r-Ti3C2Tx) increased the shielding effectiveness (SE) by 7.26% and the absorption (SEA) was greatly enhanced by the ant farm like structure. The composites possess excellent thermal and EMI SE characteristics, thus can be applied in areas, such as mobile phones, military utensils, heat-emitting electronic devices, automobiles and radars.
机译:MXENE和导电聚合物是用于电磁干扰屏蔽(EMI)应用的吸引力候选者。通过经济高效的喷涂技术制造MXENE-PAT导电聚合物(CP)复合材料,并使用X射线光电子能谱(XPS),扫描电子显微镜(SEM),X射线衍射(XRD)和拉曼光谱法。已经开发了一种用于合成剥落的MXENE的新方法。 MXENE-PAT-聚(p-氨基酚) - 聚苯胺共聚物复合材料表现出7.813厘米(-1)的良好电导率(EC)。复合材料显示出优异的热性能,其为0.687W(m k)( - 1)导热率,2.247 j(g k)( - 1)热容量,0.282mm(2)s(-1)热扩散率和1.330 W S(1/2)m(-2)k-1热力共生性。复合材料显示出99.99%的屏蔽效率,MXENE-PAT-PAPAP复合材料(MXPATPA)在8.2GHz时具有45.18 dB的EMI屏蔽效果。减少的m烯(R-Ti3C2Tx)的形式提高了屏蔽效果(SE)的屏蔽效果7.26%,并且蚂蚁农场结构大大提高了吸收(海)。复合材料具有出色的热和EMI SE特性,因此可以应用于手机,军用用具,发热电子设备,汽车和雷达等领域。

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  • 来源
    《RSC Advances》 |2020年第3期|共21页
  • 作者单位

    Wonkwang Univ Coll Nat Sci Div Bionanochem Iksan 570749 South Korea;

    Wonkwang Univ Coll Nat Sci Div Bionanochem Iksan 570749 South Korea;

    Wonkwang Univ Dept Chem Engn Iksan 570749 South Korea;

    KETI Researcher IT Applicat Res Ctr Seongnam South Korea;

    Korea Inst Mat Sci Composite Res Div Chang Won 51508 South Korea;

    KETI Researcher IT Applicat Res Ctr Seongnam South Korea;

    Wonkwang Univ Coll Nat Sci Div Bionanochem Iksan 570749 South Korea;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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