Platinum-(phosphinito-phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines

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Platinum-(phosphinito-phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines

机译：铂 - （磷碱 - 磷酸酸）复合物作为双天赋的哌啶醇氧化片段化的催化剂：对伯胺的进入

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Platinum-(phosphinito-phosphinous acid) complex catalyzes the oxidative fragmentation of hindered piperidinols according to a hydrogen transfer induced methodology. This catalyst acts successively as both a hydrogen carrier and soft Lewis acid in a one pot - two steps process. This method can be applied to the synthesis of a wide variety of primary amines in a pure form by a simple acid-base extraction without further purification.

机译：铂 - （磷碱 - 磷酸酸）复合物根据氢转移诱导的方法催化受阻哌啶酚的氧化片段化。该催化剂连续起作用氢载体和软路易斯酸在一个锅中的两个步骤过程中。该方法可以通过简单的酸碱萃取在纯形式中以纯的形式应用于整个伯胺的合成，而无需进一步纯化。

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《RSC Advances》 |2019年第65期|共5页
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1. Platinum-(phosphinito-phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines [J] . RSC Advances . 2019,第65期

机译：铂 - （磷碱 - 磷酸酸）复合物作为双天赋的哌啶醇氧化片段化的催化剂：对伯胺的进入
2. Metal-Free: A Novel and Efficient Aerobic Oxidation of Primary Amines to Oximes Using N,N',N"-Trihydroxyisocyanuric Acid and Acetaldoxime as Catalysts in Water [J] . Jiatao Yu, Ming Lu Synlett . 2014,第13期

机译：无金属：使用N，N'，N“-三羟基异氰尿酸和乙醛肟作为催化剂在水中新型胺的新型有效氧氧化制肟
3. Iron oligopyridiee complexes as efficient catalysts for practical oxidation of arenes, alkanes, tertiary amines and N-acyl cyclic amines with Oxone [J] . Peng Liu, Yungen Liu, Ella Lai-Ming Wong Chemical science . 2011,第11期

机译：寡吡啶铁络合物可作为有效的催化剂，用于使用Oxone实际氧化芳烃，烷烃，叔胺和N-酰基环胺
4. Zeolite-confined Mn complexes of cyclic amines: New selective catalysts for hydrocarbon oxidation [C] . D. E. De Vos, J. Meinershagen, T. Bein International congress on catalysis;ICC . 1996

机译：沸石限制的环胺锰配合物：新型的烃氧化选择性催化剂
5. Reactivity studies of platinum(IV) hydroxide and methoxide complexes and the study of pincer palladium(II) complexes as potential catalysts for olefin epoxidation [D] . Smythe, Nicole 2004

机译：氢氧化铂（IV）和甲醇盐配合物的反应性研究以及钳夹钯（II）配合物作为烯烃环氧化潜在催化剂的研究
6. Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation [O] . Xiuquan Jia, Jiping Ma, Fei Xia, -1

机译：用乙酰丙酮转换锰氧化物催化剂上的酸度以进行选择性可调的胺氧化
7. Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines [O] . Romain Membrat, Alexandre Vasseur, Delphine Moraleda, 2019

机译：铂 - （磷碱 - 磷酸酸）复合物作为双天赋的哌啶醇氧化片段化的催化剂：对伯胺的进入
8. Studies of the Complexes Formed Between the 5-Trifluoromethyletetrazol Anion and Some Divalent Transition Metal Ions. Magnetochemical and Spectral Studies of Some Copper (II) Complexes of Substituted Benzoic Acids. Copper (II) Halide Complexes with Substituted Pyridine n-Oxides [R] . Harris, A. D., Jonassen, H. B., Mallory, T. L., 1964

机译：5-三氟甲基四唑阴离子与一些二价过渡金属离子形成的配合物的研究。一些取代苯甲酸铜（Ⅱ）配合物的磁化学和光谱研究。具有取代的吡啶n-氧化物的铜（II）卤化物配合物

Platinum-(phosphinito-phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines

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