CSSF-CLIP-HSQMBC: measurement of heteronuclear coupling constants in severely crowded spectral regions

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CSSF-CLIP-HSQMBC: measurement of heteronuclear coupling constants in severely crowded spectral regions

机译：CSSF-CLIP-HSQMBC：在严重拥挤的光谱区域中测量异核耦合常数

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A new pulse program development, a chemical shift selective filtration clean in-phase HSQMBC (CSSF-CLIP-HSQMBC), is presented for the user-friendly measurement of long-range heteronuclear coupling constants in severely crowded spectral regions. The introduction of the chemical shift selective filter makes the experiment extremely efficient at resolving overlapped multiplets and produces a clean selective CLIP-HSQMBC spectrum, in which the desired coupling constants can easily be measured as an extra proton-carbon splitting in f2. The pulse sequence is also provided as a real-time homonuclear decoupled version in which the heteronuclear coupling constant can be directly measured as the peak splitting in f2. The same principle is readily applicable to IPAP and AP versions of the same sequence as well as the optional TOCSY transfer, or in principle to any other selective heteronuclear experiment that relies on a clean H-1 multiplet.

机译：一种新的脉冲程序开发，一种化学变换选择性过滤清洁阶段的HSQMBC（CSSF-CLIP-HSQMBC），用于在严重拥挤的光谱区域中的远程异核耦合常数的用户友好测量。化学变换选择性滤波器的引入使实验在分辨重叠的多重方案中非常有效，并产生清洁的选择性夹子-HSQMBC光谱，其中可以容易地测量所需的耦合常数作为F2中的额外质子 - 碳分裂。还提供脉冲序列作为实时同性核去耦版本，其中可以直接测量异核耦合常数作为F2中的峰值分裂。同样的原理是适用于同一序列的IPAP和AP版本以及可选的Tocsy转移，或原则上的任何其他选择性异常转移的原则，或原则上依赖于清洁的H-1多功能。

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《RSC Advances》 |2019年第62期|共6页
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中图分类化学;
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1. CSSF-CLIP-HSQMBC: measurement of heteronuclear coupling constants in severely crowded spectral regions [J] . RSC Advances . 2019,第62期

机译：CSSF-CLIP-HSQMBC：在严重拥挤的光谱区域中测量异核耦合常数
2. Phase sensitive 3D J-resolved HMBC experiment for spectral assignment and measurement of long-range heteronuclear coupling constants [J] . Sze KH., Kong XM., Che CT., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999,第30期

机译：相敏感的3D J解析HMBC实验，用于光谱分配和远程异核耦合常数的测量
3. Selective measurement of ^{11 H– ^{11 H scalar couplings from crowded chemical shift regions: Combined pure shift and spin‐echo modulation approach}} [J] . Kakita Veera Mohana Rao, Jerripothula Kanaka Mahalakshmi, Vemulapalli Sahithya Phani Babu, Magnetic Resonance in Chemistry: MRC . 2018,第10Speca期

机译：选择性测量^{1 1 h- ^{1 1 H叠标耦合来自拥挤的化学换档区域：纯换档和自旋回声调制方法}}
4. Deducing Chemical Reaction Rate Constants and Their Regions of Confidence from Noisy Measurements of Time Series of Concentration [C] . Lecca P., Palmisano A., Priami C. Computer Modelling and Simulation, 2009. UKSIM '09 . 2009

机译：从浓度时间序列的噪声测量推导化学反应速率常数及其置信区域
5. Temporal-Spectral Characterization and Classification of Marine Mammal Vocalizations and Diesel-Electric Ships Radiated Sound over Continental Shelf Scale Regions with Coherent Hydrophone Array Measurements [D] . Huang, Wei. 2017

机译：用相干水听器阵列测量在大陆架尺度区域内声音对海洋哺乳动物发声和柴油船辐射声音的时间谱特征和分类
6. Precise Measurement of Long-Range Heteronuclear Coupling Constants by a Novel Broadband Proton–Proton-Decoupled CPMG-HSQMBC Method [O] . István Timári, Tünde Z Illyés, Ralph W Adams, -1

机译：新型宽带质子-质子解耦CPMG-HSQMBC方法精确测量长程异核耦合常数
7. Accurate measurement of heteronuclear long-range coupling constants from 1D-subspectra in crowded spectral regions [O] . Bazzo R, Barbato G, Cicero DO 1995

机译：在拥挤的光谱区域中从一维亚谱准确测量异核远程耦合常数
8. Measurements of the optical constants of magnesium oxide and calcium tungstate in the spectral region between 10-cm-1 and 100 cm-1 at 300 deg k and 90 deg k [R] . Rowntree, R. F. 1963

机译：氧化镁和钨酸钙在10 cm -1和100 cm-1之间在300°C和90°k光谱范围内的光学常数的测量

CSSF-CLIP-HSQMBC: measurement of heteronuclear coupling constants in severely crowded spectral regions

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