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Reducing leakage current and dielectric losses of electroactive polymers through electro-annealing for high-voltage actuation

机译:通过用于高压致动的电退火减少电活性聚合物的漏电流和介电损耗

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摘要

Electroactive polymers (EAPs) such as P(VDF-TrFE-CTFE) are very promising in the field of flexible sensors and actuators. Their advantages in smart electrical devices are due to their low cost, elastic properties, low density, and ability to be manufactured into various shapes and thicknesses. In earlier years, terpolymer P(VDF-TrFE-CTFE) attracted a lot of research due to its relaxor-ferroelectric property that exhibits high electrostriction phenomena. While widely used in flexible actuation, this class of material is still limited by the high electric fields required (30 V m(-1)) to achieve sufficient strain levels (>2%). This inevitably leads to high levels of leakage current and thus a short lifetime. This paper proposes a new approach based on electro-annealing thermal treatment for a pure terpolymer P(VDF-TrFE-CTFE) matrix in order to limit the conduction mechanisms. This in turn reduces the dielectric losses at a high level of electric fields. The experimental results demonstrate that a huge decrease in leakage current of 80% is achieved for a wide range of electric fields (i.e. up to 90 V m(-1)) with a 4-fold extension in time-to-breakdown at high voltage excitations of 40 V m(-1).
机译:电活性聚合物(EAP)如P(VDF-TRFE-CTFE)在柔性传感器和致动器领域非常有前途。它们在智能电气设备中的优点是由于它们的低成本,弹性,低密度,以及制造成各种形状和厚度的能力。在早期,Terpolymer P(VD​​F-TRFE-CTFE)由于其具有高电伸缩现象的松弛剂 - 铁电特性而吸引了大量研究。虽然广泛用于灵活的致动,但这类材料仍然受所需的高电场(30V m(-1))的限制,以获得足够的应变水平(> 2%)。这不可避免地导致高水平的泄漏电流,因此是短寿命。本文提出了一种基于用于纯三元聚合物P(VDF-TRFE-CTFE)基质的电退火热处理的新方法,以限制导电机构。这反过来又降低了高水平的电场处的介电损耗。实验结果表明,对于多种电场(即高达90V m(-1)),实现了80%的漏电流的巨大降低,并且在高压下突破4倍的延伸激发40 V m(-1)。

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  • 来源
    《RSC Advances》 |2019年第23期|共13页
  • 作者单位

    Univ Lyon INSA Lyon LGEF EA682 F-69621 Villeurbanne France;

    Solvay Specialty Polymers Viale Lombardia 20 I-20021 Bollate Italy;

    Univ Lyon INSA Lyon LGEF EA682 F-69621 Villeurbanne France;

    CNRS Rhodia Solvay P2D UMR 5268 85 Ave Freres Perret F-69192 St Fons France;

    Univ Lyon INSA Lyon LGEF EA682 F-69621 Villeurbanne France;

    Univ Lyon INSA Lyon LGEF EA682 F-69621 Villeurbanne France;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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