首页> 外文期刊>RSC Advances >Association of liquid-assisted grinding with aging accelerates the inherently slow slipping-on of a dibenzo-24-crown-8 over the N-hydroxysuccinimide ester of an ammonium-containing thread
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Association of liquid-assisted grinding with aging accelerates the inherently slow slipping-on of a dibenzo-24-crown-8 over the N-hydroxysuccinimide ester of an ammonium-containing thread

机译:液体辅助研磨与老化的结合加速了在含铵螺纹的N-羟基琥珀酰亚胺酯上的二苯并-24-冠-8的固有慢滑动

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摘要

Solvent-free and solvent-less slipping-on of the dibenzo-24-crown-8 (DB24C8) over the N-hydroxysuccinimide end of an ammonium-containing thread has been studied and compared to the same reaction operated in solution. Slippage proved to be possible in solvent-free conditions, but the fastest slippage was obtained under heating when preliminary Liquid-Assisted Grinding (LAG) conditions were applied to the reactants followed by aging under an atmosphere of acetonitrile.
机译:已经研究了在含铵螺纹的N-羟基琥珀酰亚胺末端的无溶剂和溶剂的溶剂 - 在含铵螺纹的N-羟基琥珀酰亚胺末端进行了研究,并与在溶液中操作的相同反应进行比较。 在无溶剂条件下,滑动被证明是可能的,但是当初步液体辅助研磨(LAG)条件施加到反应物中时,在加热下获得最快的滑动,然后在乙腈气氛下老化。

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  • 来源
    《RSC Advances》 |2019年第37期|共4页
  • 作者单位

    Univ Montpellier Supramol Machines &

    ARchitectures Team CNRS IBMM ENSCM UMR 5247 Fac Sci Case Courrier 1706 Batiment Chim 17 3eme Etage F-34095 Montpellier 5 France;

    Univ Montpellier Green Chem &

    Enabling Technol Team Inst Biomol Max Mousseron UMR 5247 CNRS ENSCM Site Triolet Pl Eugene Bataillon F-34095 Montpellier 5 France;

    Univ Montpellier Green Chem &

    Enabling Technol Team Inst Biomol Max Mousseron UMR 5247 CNRS ENSCM Site Triolet Pl Eugene Bataillon F-34095 Montpellier 5 France;

    Univ Montpellier Supramol Machines &

    ARchitectures Team CNRS IBMM ENSCM UMR 5247 Fac Sci Case Courrier 1706 Batiment Chim 17 3eme Etage F-34095 Montpellier 5 France;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
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