Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives

Genc Hayriye Nevin

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Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives

机译：通过手性四氧环碱催化的偶联型髓鞘反应[2]芳烃[2]三嗪衍生物

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A highly enantioselective Michael addition reaction of anthrone with nitroalkenes by chiral tetraoxacalix[2]arene[2]triazine catalysts was investigated as a novel topic. The stereoselective conversion progressed smoothly by employing 10 mol% of the catalyst and afforded the corresponding Michael adducts with acceptable to high enantioselectivities (up to 97% ee) and very high yields (up to 96%).

机译：通过手性四氧化碱[2]芳烯与硝基链酮与硝基烷烃的高映射性迈克尔加成反应[2]芳烃[2]三嗪催化剂作为新颖的话题。通过使用10摩尔％的催化剂来平稳地进行立体选择性转化，并得到相应的迈克尔加合物，其具有可接受的高映射性（高达97％EE）和非常高的收率（高达96％）。

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《RSC Advances》 |2019年第36期|共7页
作者
Genc Hayriye Nevin;
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Necmettin Erbakan Univ AK Educ Fac Dept Sci Educ TR-42090 Konya Turkey;

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正文语种 eng
中图分类化学;
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1. Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives [J] . Genc Hayriye Nevin RSC Advances . 2019,第36期

机译：通过手性四氧环碱催化的偶联型髓鞘反应[2]芳烃[2]三嗪衍生物
2. Design, synthesis and application of chiral tetraoxacalix[2]arene[2]triazine‐based organocatalysts in asymmetric Michael addition reactions [J] . Genc Hayriye Nevin, Ozgun Ummu, Sirit Abdulkadir Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry . 2019,第4期

机译：手性四氧基碱[2]芳烃[2]三嗪类有机催化剂的设计，合成及应用在不对称迈克尔加法反应中
3. Chiral tetraoxacalix[2]arene[2]triazine-based organocatalysts for Enantioselective Aldol reactions [J] . Genc Hayriye Nevin, Ozgun Ummu, Sirit Abdulkadir Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2019,第27期

机译：手性四氧化碱[2]芳烃[2]三嗪类有机催化剂用于对映选择性的醛醇反应
4. Ruthenium-Catalyzed Enantioselective Carbon-Carbon Bond Forming Reaction via Allenylidene-Ene Process: Synthetic Approach to Chiral Heterocycles such as Chromane, Thiochromane, and 1,2,3,4-Tetrahydroquinoline Derivatives [C] . Koii Fukamizu, Yoshihiro Miyake, Yoshiaki Nishibayashi Symposium on Organometallic Chemistry . 2008

机译：通过联苯胺 - 烯丙基 - 烯丙基 - 烯丙基烯丙基催化的对映选择性碳 - 碳键形成反应：合成杂环如铬杂环，如铬杂环烷，噻吩铵盐和1,2,3,4-四氢喹啉衍生物
5. Asymmetric Mannich reactions catalyzed by urea derivatives for the enantioselective preparation of beta-aryl-beta-amino acid derivatives. [D] . Wenzel, Anna G. 2004

机译：由脲衍生物催化的不对称曼尼希反应用于对映选择性制备β-芳基-β-氨基酸衍生物。
6. One-Pot Synthesis of Novel Chiral β-Amino Acid Derivatives by Enantioselective Mannich Reactions Catalyzed by Squaramide Cinchona Alkaloids [O] . Kankan Zhang, Xueping Liang, Ming He, 2013

机译：方酸金鸡纳生物碱催化对映选择性曼尼希反应一锅法合成新型手性β-氨基酸衍生物
7. Chiral Bicyclic Guanidine-Catalyzed Enantioselective Reactions of Anthrones [O] . -1

机译：手性双环胍催化促进促进促进促进的促论性反应

Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives

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