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Highly transparent copper iodide thin film thermoelectric generator on a flexible substrate

机译:高度透明的铜碘化物薄膜热电发电机在柔性基板上

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摘要

Simultaneously transparent and flexible conductive materials are in demand to follow the current trend in flexible technology. The search for materials with compliant optoelectronic properties, while simultaneously retaining their electric conductivity at high strain deformation, comprises promising opportunities in modern nanotechnology. Copper iodide (CuI) is not only the most transparent and highly conductive p-type material, but its optimization has contributed to improved ZT values in planar thin-film thermoelectrics. In this work, the readiness of CuI thin films to transparent, flexible technology is evidenced. A maximum ZT value of 0.29 for single CuI thin films of ca. 300 nm in thickness is reported. Values of open-circuit voltage V-oc, short circuit current I-sc and power output of p-n thermoelectric modules of Gallium-doped zinc oxide (GZO) and CuI thin films deposited on a transparent flexible Kapton (R) (type CS) substrate are reported, and a prototype of a flexible transparent thermoelectric generator based on 17 p-n modules was constructed. Bending analysis of CuI thin films reveals interesting, distinct results when submitted to compression and tension analysis - a behaviour not seen in conventional semiconducting thin films under equivalent strain conditions. A plausible account for such diversity is also included.
机译:同时透明和柔性的导电材料需要遵循灵活技术的当前趋势。寻找具有柔顺光电性质的材料,同时在高应变变形处同时保持其电导率,包括在现代纳米技术中的有希望的机会。碘化铜(CUI)不仅是最透明且导电的P型材料,而且其优化已经有助于改进平面薄膜热电中的ZT值。在这项工作中,Cui薄膜对透明,灵活的技术的准备证明了。对于CA的单杯薄膜,最大ZT值为0.29。报道厚度为300nm。开路电压V-OC的值,短路电流I-SC和PN热电模块的PN热电模块的功率输出和沉积在透明柔性Kapton(r)(型Cs)衬底上的Cui薄膜报道,构建了基于17个PN模块的柔性透明热电发电机的原型。 Cui薄膜的弯曲分析显示在提交压缩和张力分析时揭示有趣,不同的结果 - 在等效应变条件下在常规半导体薄膜中未见的行为。还包括这种多样性的合理账户。

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    《RSC Advances》 |2019年第61期|共8页
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  • 正文语种 eng
  • 中图分类 化学;
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