One pot conversion of glucose to ethyl levulinate over a porous hydrothermal acid catalyst in green solvents

Bosilj Monika; Schmidt Johannes; Fischer Anna; White Robin J.

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One pot conversion of glucose to ethyl levulinate over a porous hydrothermal acid catalyst in green solvents

机译：绿色溶剂多孔水热酸催化剂上葡萄糖转化葡萄糖转化为乙酸乙基乙烯

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The one-pot conversion of glucose to ethyl levulinate over an acid-functionalised hydrothermal catalyst (derived from glucose) provides high initial yields up to 37 mol%, comparable to the homogeneous H2SO4 catalyst, whilst catalyst performance is strongly influenced by green solvent choice.

机译：在酸官能化的水热催化剂（衍生自葡萄糖）上乙酸乙酸乙酯的单罐转化为高达37摩尔％的高初始产率，与均相H2SO4催化剂相当，催化剂性能受到绿色溶剂选择的强烈影响。

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《RSC Advances》 |2019年第35期|共4页
作者
Bosilj Monika; Schmidt Johannes; Fischer Anna; White Robin J.;
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Fraunhofer Inst Solar Energy Syst ISE Heidenhofstr 2 D-79110 Freiburg Germany;

Tech Univ Berlin Fak Inst Chem 2 Sekretariat BA 2 Hardenbergstr 40 D-10623 Berlin Germany;

Univ Freiburg Dept Inorgan &

Analyt Chem Albertstr 21 D-79104 Freiburg Germany;

Fraunhofer Inst Solar Energy Syst ISE Heidenhofstr 2 D-79110 Freiburg Germany;

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正文语种 eng
中图分类化学;
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1. One pot conversion of glucose to ethyl levulinate over a porous hydrothermal acid catalyst in green solvents [J] . Bosilj Monika, Schmidt Johannes, Fischer Anna, RSC Advances . 2019,第35期

机译：绿色溶剂多孔水热酸催化剂上葡萄糖转化葡萄糖转化为乙酸乙基乙烯
2. One pot conversion of glucose to ethyl levulinate over a porous hydrothermal acid catalyst in green solvents [J] . Monika Bosilj, Johannes Schmidt, Anna Fischer, RSC Advances . 2019,第35期

机译：在绿色溶剂中通过多孔水热酸催化剂将葡萄糖一锅转化为乙酰丙酸乙酯
3. One pot conversion of glucose to ethyl levulinate over a porous hydrothermal acid catalyst in green solvents [J] . Monika Bosilj, Johannes Schmidt, Anna Fischer, RSC Advances . 2019,第35期

机译：在绿色溶剂中通过多孔水热酸催化剂将葡萄糖一锅转化为乙酰丙酸乙酯
4. Hydrothermal conversion of glucose into lactic acid with nickel as a catalyst [C] . YOUSIF S. ADAMA, XU ZENG, FANGMING JIN, International Conference on Energy, Environment and Sustainable Development . 2012

机译：葡萄糖将葡萄糖转化为乳酸与镍作为催化剂
5. New developments toward the synthesis of heterocycles and applications in green chemistry. I. A simple and essentially one-pot synthesis of N-aminated heterocycles using phase transfer catalyst (Aliquat-336). II. Synthesis of pharmaceutically important pyrrole derivatives. III. Applications in green chemistry: Surfactant-mediated environmentally friendly cleavage of aromatic esters and trans-esterification under solvent-free neutral conditions . [D] . Patel, Nitinchandra. 2005

机译：杂环合成的新进展及其在绿色化学中的应用。 I.使用相转移催化剂（Aliquat-336）简单且基本上一锅合成N-胺化的杂环。二。药学上重要的吡咯衍生物的合成。三，在绿色化学中的应用：在无溶剂的中性条件下，表面活性剂介导的环境友好的芳族酯裂解和酯交换反应。
6. Conversion of Furfuryl Alcohol into Ethyl Levulinate over Glucose-Derived Carbon-Based Solid Acid in Ethanol [O] . Geng Zhao, Ming Liu, Xinkui Xia, 2019

机译：乙醇中葡萄糖衍生的碳基固体酸将糠醇转化为乙酰丙酸乙酯
7. Conformal sulfated zirconia monolayer catalysts for the one-pot synthesis of ethyl levulinate from glucose [O] . Morales, Gabriel, Osatiashtiani, Amin, Hernandez, Blanca, 2014

机译：用于葡萄糖一锅法合成乙酰丙酸乙酯的共形硫酸盐氧化锆单层催化剂

One pot conversion of glucose to ethyl levulinate over a porous hydrothermal acid catalyst in green solvents

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