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Synthesis of high surface area porous carbon from anaerobic digestate and it's electrochemical study as an electrode material for ultracapacitors

机译:从厌氧消化物中合成高表面积多孔碳,电化学研究作为超超容器的电极材料

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The remnants of the anaerobic digestion process, 'the digestate,' mainly consist of fibrous lignin and cellulose like molecules, as a significant carbon repository along with some other inorganic impurities. The present work demonstrates the potential use of anaerobically treated fruit and vegetable waste (FVW) as a source of porous carbon for supercapacitor electrode materials. This work suggests that the FVW digestate can inherit silicon (Si) and calcium (Ca) based inorganic impurities, which play an essential role as structure directing agents for digestate derived carbon. These contaminants act as hard templates during carbonization to create hierarchical pores and contribute to an enhancement in surface area. Different batches from an anaerobic biogas digester plant are converted to porous carbon and examined as a potential supercapacitor electrode material. A maximum capacitance of 235 F g(-1) is achieved from DDHPC-4kh carbon with a specific surface area of 2502 m(2) g(-1) at a current density of 1 A g(-1) in an acidic aqueous electrolyte. The results are significant in comparison to other bio-sourced precursors studied previously.
机译:厌氧消化过程的残余物,'消化物'主要由纤维木质素和纤维素等分子组成,与一些其他无机杂质一起作为显着的碳储存。本作者证明了厌氧处理的水果和蔬菜废物(FVW)作为超级电容器电极材料的多孔碳源的潜在使用。这项工作表明FVW消化可以继承基于硅(Si)和基于钙(CA)的无机杂质,这起到用于消化衍生碳的结构指示剂的基本作用。这些污染物在碳化过程中充当硬模板,以产生分层孔隙并有助于表面积的增强。来自厌氧沼气挖掘机植物的不同批次被转化为多孔碳,并作为潜在的超级电容器电极材料检查。从DDHPC-4KH碳的最大电容为235V(-1),在酸性水性中的电流密度为2502m(2)g(-1)的比表面积为2502μm(2)g(-1)电解质。结果与先前研究的其他生物源前体相比,结果是显着的。

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    《RSC Advances》 |2019年第62期|共8页
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  • 正文语种 eng
  • 中图分类 化学;
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