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The effect of a trimetallic nanocomposite in the solar absorber layer of organic solar cells

机译:三相纳米复合材料在有机太阳能电池太阳能吸收层中的影响

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摘要

Bulk heterojunction (BHJ) organic solar cells were fabricated using a trimetallic nanocomposite (Ag : Zn : Ni) in the photoactive layer. The incorporation of the nanocomposite was limited to the concentrations of 4% and 6% by volume into poly(3-hexylthiophene) (P3HT) and 6-6-phenyl-C61-butyric acid methyl ester (PCBM) blend solar absorber. The newly fabricated devices were investigated in terms of the optical, electrical and morphological properties of the photoactive medium. The power conversion efficiencies (PCE) of the solar cells were found to be increased by 57% and 84% due to improved harvesting of solar radiation due to the occurrence of localized surface plasmon resonance (LSPR) effects of the metal nanocomposite. Silver : zinc : nickel (Ag : Zn : Ni) tri-metallic nanocomposites were synthesized using a chemical reduction method from silver, zinc and nickel nitrates. The nanocomposites were characterized in terms of morphology, elemental composition and crystallinity which are extensively discussed in the manuscript.
机译:在光活性层中使用三种子型纳米复合材料(Ag:Zn:Ni)制造散装异质结(BHJ)有机太阳能电池。将纳米复合材料的掺入仅限于聚(3-己基噻吩)(P3HT)和6-6苯基-C61-丁酸甲酯(PCBM)混合太阳能吸收剂中的4%和6重量%的浓度。在光活性培养基的光学,电气和形态学方面研究了新制造的装置。由于金属纳米复合材料的局部表面等离子体共振(LSPR)效应的发生,因此发现太阳能电池的功率转换效率(PCE)增加了57%和84%。银:锌:镍(Ag:Zn:Ni)三金属纳米复合材料由银,锌和硝酸镍的化学还原方法合成。以形态学,元素组成和结晶度表征纳米复合材料,其在稿件中广泛讨论。

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  • 来源
    《RSC Advances》 |2019年第11期|共7页
  • 作者单位

    Univ KwaZulu Natal Sch Chem &

    Phys Pietermaritzburg Campus Private Bag X01 ZA-3209 Scottsville South Africa;

    Univ KwaZulu Natal Sch Chem &

    Phys Pietermaritzburg Campus Private Bag X01 ZA-3209 Scottsville South Africa;

    Univ KwaZulu Natal Sch Chem &

    Phys Pietermaritzburg Campus Private Bag X01 ZA-3209 Scottsville South Africa;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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