Fe-II-catalysed insertion reaction of alpha-diazocarbonyls into X-H bonds (X = Si, S, N, and O) in dimethyl carbonate as a suitable solvent alternative

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Fe-II-catalysed insertion reaction of alpha-diazocarbonyls into X-H bonds (X = Si, S, N, and O) in dimethyl carbonate as a suitable solvent alternative

机译：α-二聚羰基的Fe-II催化剂插入反应在碳酸二甲酯中的X-H键（X = Si，S，N和O）中作为合适的溶剂替代方案

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The insertion reaction of a broad range of diazo compounds into Si-H bonds was found to be efficiently catalysed by Fe(OTf)(2) in an emerging green solvent i.e. dimethyl carbonate (DMC). The alpha-silylated products were obtained in good to excellent yields (up to 95%). Kinetic studies showed that the extrusion of N-2 to form an iron carbene intermediate is rate-limiting. The iron-catalysed insertion reaction of methyl alpha-phenyl-alpha-diazoacetate into polar X-H bonds (S-H, N-H, and O-H) was also established in DMC.

机译：将宽范围的重氮化合物进入Si-H键的插入反应被用Fe（OTF）（2）在新出现的绿色溶剂中有效地催化，即碳酸二甲酯（DMC）。 α-甲硅烷基化产品良好地获得优异的产率（高达95％）。动力学研究表明，N-2的挤出形成铁菜中间体是速率限制。在DMC中还建立了甲基苯基 - 苯基 - α-二氮酸甲酯甲基α-苯基 - α-二氮酸盐（S-H，N-H和O-H）的铁催化的插入反应。

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《RSC Advances》 |2019年第54期|共6页
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1. Fe-II-catalysed insertion reaction of alpha-diazocarbonyls into X-H bonds (X = Si, S, N, and O) in dimethyl carbonate as a suitable solvent alternative [J] . RSC Advances . 2019,第54期

机译：α-二聚羰基的Fe-II催化剂插入反应在碳酸二甲酯中的X-H键（X = Si，S，N和O）中作为合适的溶剂替代方案
2. Insertion Reactions of Silylenoid Ph_2SiLi(OBu-t)into X-H Bonds(X = F,OH,and NH_2) [J] . Ju Xie, Dacheng Feng, Maoxia He, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第46期

机译：硅基Ph_2SiLi（OBu-t）插入X-H键（X = F，OH和NH_2）的插入反应
3. Iron Porphyrin Catalyzed Insertion Reaction of N-Tosylhydrazone-Derived Carbenes into X-H (X = Si, Sn, Ge) Bonds [J] . Wang En-Hui, Ping Yuan-Ji, Li Zong-Rui, Organic letters . 2018,第15期

机译：铁卟啉催化N-甲苯胺腙衍生的碳酸碳盐的插入反应进入X-H（X = Si，Sn，Ge）键合
4. Why Dimethyl Carbonate Is Better Co-Solvent Than Other Linear Carbonates: Important Role of Polar Conformer Formation [C] . Hyejin Lee, Sunwook Hwang, Hochun Lee Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：为什么碳酸二甲酯比其他线性碳酸酯更好的共溶剂：极性塑造剂形成的重要作用
5. Exploration of alpha-Diazocarbonyl Compounds for Transition-Metal Catalyzed Carbon-Carbon Bond Formations. Development of Palladium-Catalyzed Stereoselective Synthesis of Trisubstituted Alkenes and the Synthesis of Quaternary alpha,alpha-Heterodiaryl Carboxylic Acids by Rhodium-Catalyzed Multi-Component Coupling Reactions. [D] . Tsoi, Yuk Tai. 2012

机译：探索用于过渡金属催化的碳-碳键形成的α-重氮羰基化合物。铑催化的多组分偶合反应在钯催化的立体选择性合成三取代的烯烃上的发展和季铵的α，α-杂二芳基羧酸的合成。
6. Proline-Catalysed Amination Reactions in Cyclic Carbonate Solvents [O] . Christopher Beattie, Michael North, Pedro Villuendas 2011

机译：环状碳酸酯溶剂中脯氨酸催化的胺化反应
7. FeII-catalysed insertion reaction of α-diazocarbonyls into X–H bonds (X = Si, S, N, and O) in dimethyl carbonate as a suitable solvent alternative [O] . Nour Tanbouza, Hoda Keipour, Thierry Ollevier 2019

机译：α-二聚羰基的Feii-催化在碳酸二甲酯中的X-H键（X = Si，S，N和O）中的X-H键（x = Si，S，N和O）作为合适的溶剂替代方案
8. Reactions of 1,1-Dimethyl-2,3-Bis(trimethylsilyl)-1-Silirene and Hexamethylsilirane with Dimethyl Sulfoxide. Insertion of Dimethylsilanone into the Silirene and Silirane Rings. [R] . Seyferth, D., Lim, T. F. O., Duncan, D. P. 1977

机译：1,1-二甲基-2,3-双（三甲基甲硅烷基）-1-硅烷和六甲基硅烷与二甲基亚砜的反应。将二甲基硅烷酮插入silirene和silirane环中。

Fe-II-catalysed insertion reaction of alpha-diazocarbonyls into X-H bonds (X = Si, S, N, and O) in dimethyl carbonate as a suitable solvent alternative

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