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Acetylacetone functionalized magnetic carbon microspheres for the highly-efficient adsorption of heavy metal ions from aqueous solutions

机译:乙酰丙酮官能化碳微球,用于高效吸附来自水溶液的重金属离子

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摘要

Herein, Acac-C@Fe3O4, a magnetic carbon (C@Fe3O4) modified with acetylacetone (Acac), was first prepared and used as a solid-phase adsorbent for adsorbing some heavy metal ions from aqueous solution. The adsorbent was characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), vibrating sample magnetometry (VSM) and BET studies. Some parameters affecting the adsorption and desorption processes were studied in Pb2+ solution, including sample pH, contact time, initial concentration, type and connection of the desorption solution. Absorption results showed that removal of Pb2+ was 100% under optimal conditions at an initial concentration of 10.0 mg L-1. The adsorption mechanism conformed well to a pseudo-second order kinetic model. The adsorption capacity of the sorbent also showed promising results with Hg2+, Cr3+, Fe2+, Cd2+, Mn2+, Zn2+, Cu2+ and Pb2+, where maximum adsorption capacities reached 98.0, 151.2, 188.9, 202.2, 286.3, 297.2, 305.1 and 345.3 mg g(-1), respectively. The Acac-C@Fe3O4 microsphere material was successfully applied to the adsorption of heavy metal ions in aqueous solution.
机译:在此,首先制备用乙酰丙酮(ACAC)改性的磁性碳(C 2 Fe3O4),并用作固相吸附剂,用于吸附来自水溶液的一些重金属离子。吸附剂的特征在于傅里叶变换红外光谱(FTIR),X射线衍射(XRD),扫描电子显微镜(SEM),透射电子显微镜(TEM),X射线光电子能谱(XPS),振动样品磁体(VSM)和BET研究。在PB2 +溶液中研究了影响吸附和解吸过程的一些参数,包括样品pH,接触时间,初始浓度,类型和解吸溶液的连接。吸收结果表明,在最佳条件下,在初始浓度为10.0mg l-1的最佳条件下除去Pb2 +为100%。吸附机制符合伪二阶动力学模型。吸附剂的吸附能力也表现出有前途的与汞+,Cr3 +的,Fe2 +的,镉,MN2 +,Zn2 +的,Cu 2+和Pb2 +的,其中最大的吸附容量达到98.0,151.2,188.9,202.2,286.3,297.2,305.1和345.3毫克克结果( -1)分别。 ACAC-C @ Fe3O4微球材料成功地应用于水溶液中重金属离子的吸附。

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  • 来源
    《RSC Advances》 |2019年第6期|共8页
  • 作者单位

    Univ Shanghai Sci &

    Technol Coll Sci Shanghai 200093 Peoples R China;

    Univ Shanghai Sci &

    Technol Coll Sci Shanghai 200093 Peoples R China;

    Univ Shanghai Sci &

    Technol Coll Sci Shanghai 200093 Peoples R China;

    Univ Shanghai Sci &

    Technol Coll Sci Shanghai 200093 Peoples R China;

    Univ Shanghai Sci &

    Technol Coll Sci Shanghai 200093 Peoples R China;

    Univ Shanghai Sci &

    Technol Coll Sci Shanghai 200093 Peoples R China;

    Univ Shanghai Sci &

    Technol Coll Sci Shanghai 200093 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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