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Bio-inspired electrochemical corrosion coatings derived from graphene/natural lacquer composites

机译:来自石墨烯/天然漆复合材料的生物启发电化学腐蚀涂料

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摘要

Protective corrosion coatings are preferably composed of available, environmentally friendly, and low-volatility organic compounds. Herein, newexcellent corrosion graphene/raw lacquer composite coatingswere formed, in which waterborne graphene was modified by taking lignin tripolymer (LT) as an aqueous stabilizer and subsequently adding to raw lacquer (RL). Graphene/lacquer composite coatings were achieved by an ecofriendly fabrication process. The structure and thermostability of the lignin derivative were studied by Fourier transform infrared spectroscopy (FT-IR) and thermogravimetry (TG), respectively, while the composition of the LT was characterized by Raman spectrometry. And the experimental result revealed that LT was an effective graphene dispersant (LTG) up to 60 d without any precipitation. Besides, the SEM of the graphene/lacquer coatings revealed that the excellent protection properties were highly attributable to the formation of a very rough surface, because of the highly dispersed nature of the graphene nanoparticles. Also, the corrosion behavior of the composite coatings on a metal substrate were studied by polarization curve analysis and electrochemical impedance spectroscopy (EIS). According to the electrochemical corrosion tests, the lacquer composite coating with 5 wt% LTG dispersion (RL/LTG-5, containing 0.3 wt% graphene) possessed excellent corrosion resistance, making it suitable for protecting bare metal substrates.
机译:保护性腐蚀涂层优选由可用,环保和低挥发性有机化合物组成。本文中,通过将木质素三聚母(LT)作为水性稳定剂并随后加入生漆(R1)来改变形成的新细化腐蚀石墨烯/原料漆复合涂层。石墨烯/漆复合涂料是通过ECOFriendly制造方法实现的。通过傅里叶变换红外光谱(FT-IR)和热重度(Tg)研究了木质素衍生物的结构和热稳定性,而拉曼光谱法的特征在于LIC的组合物。并且实验结果表明,LT是高达60d的有效石墨烯分散剂(LTG),没有任何沉淀。此外,石墨烯/漆涂层的SEM表明,由于石墨烯纳米颗粒的高度分散性,优异的保护性能高度可归因于形成非常粗糙的表面。而且,通过偏振曲线分析和电化学阻抗光谱(EIS)研究了金属基材上的复合涂层的腐蚀行为。根据电化学腐蚀试验,具有5wt%LTG分散体(含有0.3wt%石墨烯的RL / LTG-5)的漆复合涂层具有优异的耐腐蚀性,使其适用于保护裸金属基材。

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  • 来源
    《RSC Advances》 |2017年第71期|共11页
  • 作者单位

    Fujian Normal Univ Coll Mat Sci &

    Engn Fuzhou 350007 Fujian Peoples R China;

    Fujian Normal Univ Coll Mat Sci &

    Engn Fuzhou 350007 Fujian Peoples R China;

    Fujian Normal Univ Coll Mat Sci &

    Engn Fuzhou 350007 Fujian Peoples R China;

    Fujian Normal Univ Coll Mat Sci &

    Engn Fuzhou 350007 Fujian Peoples R China;

    Fujian Normal Univ Coll Mat Sci &

    Engn Fuzhou 350007 Fujian Peoples R China;

    Fujian Normal Univ Coll Mat Sci &

    Engn Fuzhou 350007 Fujian Peoples R China;

    Fujian Normal Univ Coll Mat Sci &

    Engn Fuzhou 350007 Fujian Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
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