Practical stability of Au-25(SR)(18)(-1/0/+1)

Collins C. B.; Tofanelli M. A.; Crook M. F.; Phillips B. D.; Ackerson C. J.

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Practical stability of Au-25(SR)(18)(-1/0/+1)

机译：AU-25（SR）（18）（ - 1/0 / + 1）的实用稳定性

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Superatom electron shell and/or geometric shell filling underlies the thermodynamic stability of coinage and alkali metal clusters in both theoretical and experimental results. Factors beyond simple shell filling contribute substantially to the lifetime of ligated clusters in solution. Such factors include the nature of the solvent, the atmosphere and the steric size of the ligand shell. Here we systematically lay out a 'practical' stability model for ligated metal clusters, which includes both shell-closing aspects and colloidal stability aspects. Cluster decomposition may follow either fusion or fission pathways. Solvent polarity can be determinative of the decomposition pathway.

机译：超大电子壳和/或几何壳填充下层了币和碱金属簇的热力学稳定性在理论和实验结果中。超出简单壳填充的因素基本上有助于溶液中连接簇的寿命。这些因素包括溶剂的性质，气氛和配体壳的空间尺寸。在这里，我们系统地为连接的金属簇制定了“实用”稳定模型，包括壳闭合方面和胶体稳定性方面。集群分解可以遵循融合或裂变路径。溶剂极性可以是分解途径的确定性。

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《RSC Advances》 |2017年第71期|共5页
作者
Collins C. B.; Tofanelli M. A.; Crook M. F.; Phillips B. D.; Ackerson C. J.;
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Colorado State Univ Dept Chem Ft Collins CO 80523 USA;

Univ Pittsburgh Dept Chem Pittsburgh PA 15260 USA;

Binghamton Univ Dept Chem Binghamton NY 13902 USA;

Colorado State Univ Dept Chem Ft Collins CO 80523 USA;

Colorado State Univ Dept Chem Ft Collins CO 80523 USA;

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正文语种 eng
中图分类化学;
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2. Practical stability of Au-25(SR)(18)(-1/0/+1) [J] . Collins C. B., Tofanelli M. A., Crook M. F., RSC Advances . 2017,第71期

机译：AU-25（SR）（18）（ - 1/0 / + 1）的实用稳定性
3. A Single Model for the Excited-State Dynamics of Au-18(SR)(14) and Au-25(SR)(18) Clusters [J] . Yousefalizadeh Goonay, Stamplecoskie Kevin G. The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2018,第35期

机译：用于AU-18（SR）（14）和AU-25（SR）（18）集群的励磁状态动态的单一模型
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7. Practical Stability of Au25(SR)18−1/0/+1 [O] . C. B. Collins, M. A. Tofanelli, M. F. Crook, -1

机译：Au25（SR）18−1 / 0 / + 1的实用稳定性
8. (1RS,4SR,8SR,11RS,15SR,18RS,22RS,25SR)-1,4:8,11:15,18:22,25-Tetraethano-29H,31H-tetrabenzob,g,l,qporphine chloroform disolvate [O] . Shinji Aramaki, Yoshimasa Sakai, Hiroyuki Yanagisawa, 2005

机译：（1RS，4SR，8SR，11R，15SR，18R，22RS，25SR）-1,4：8,11：15,18：22,25-四乙醇-29H，31H-四强B，G，L，Q卟啉氯仿脱溶水

Practical stability of Au-25(SR)(18)(-1/0/+1)

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